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The oxidation numbers of phosphorus in B...

The oxidation numbers of phosphorus in `Ba(H_2PO_2)_2` and xenon in `Na_4XeO_6` are respectively

A

`+3 and +4`

B

`+2 and +6`

C

`+1 and +8`

D

`-1 and -6`

Text Solution

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The correct Answer is:
To find the oxidation numbers of phosphorus in \( Ba(H_2PO_2)_2 \) and xenon in \( Na_4XeO_6 \), we will follow these steps: ### Step 1: Determine the oxidation number of phosphorus in \( Ba(H_2PO_2)_2 \) 1. **Identify the components of the compound**: - The compound can be dissociated into \( Ba^{2+} \) and \( H_2PO_2^{-} \). 2. **Assign oxidation states**: - Barium (Ba) has an oxidation state of +2. - Hydrogen (H) has an oxidation state of +1. - Oxygen (O) has an oxidation state of -2. 3. **Set up the equation**: - The overall charge of \( H_2PO_2^{-} \) is -1. - Let the oxidation state of phosphorus (P) be \( x \). - The equation based on the oxidation states is: \[ 2(+1) + x + 2(-2) = -1 \] - Simplifying this gives: \[ 2 + x - 4 = -1 \] \[ x - 2 = -1 \] \[ x = +1 \] ### Step 2: Determine the oxidation number of xenon in \( Na_4XeO_6 \) 1. **Identify the components of the compound**: - The compound can be analyzed as \( 4Na^{+} \) and \( XeO_6^{2-} \). 2. **Assign oxidation states**: - Sodium (Na) has an oxidation state of +1. - Oxygen (O) has an oxidation state of -2. - Let the oxidation state of xenon (Xe) be \( y \). 3. **Set up the equation**: - The overall charge of \( XeO_6^{2-} \) is -2. - The equation based on the oxidation states is: \[ y + 6(-2) = -2 \] - Simplifying this gives: \[ y - 12 = -2 \] \[ y = +10 \] ### Final Answer: - The oxidation number of phosphorus in \( Ba(H_2PO_2)_2 \) is **+1**. - The oxidation number of xenon in \( Na_4XeO_6 \) is **+10**.
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