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Aryl halides are less reactive than alky...

Aryl halides are less reactive than alkyl halides towards nuceophilic reagents. Give reasons.

A

stability of halegen atom

B

stabllity of carbonium ion

C

high boiling point

D

None of these

Text Solution

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The correct Answer is:
B
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Aryl halide is less reactive than halide towards nucleophilic substitution because

(a) An ambident nucleophile is: (i) Ammonia (ii) Ammonium ion (iii) Chloride ion (iv) Nitrite ion (b) Haloalkanes and haloarenes are organohalogen compounds. (i) Suggest a method for the preparation of alkyl chloride. (ii) Aryl halides are less reactive towards nucleophilic substitution reactions. Give reasons.

STATEMENT : Aryl halides are more reactive than alkyl towards nucleophilic substitution reaction STATEMENT : 2 Aryl halides have stronger C-X bond asa compared to alkyl halides