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In the cyanide extraction process of si...

In the cyanide extraction process of silver from argentite ore, what are the oxidizing and reducing agents used?

A

`O_(2)` and CO respectively.

B

`O_(2)` and Zn dust res pectively

C

HNO, and Zn dust respectively

D

`HNO_(3)` and CO respectively

Text Solution

Verified by Experts

The correct Answer is:
B

In the extraction of silver, `Ag_(2)` S is leached with KCN in presence of air:
`Ag_(2) S + Na CN +O_(2)`
`rarr Na [ Ag (CN_(2))_(2)] + Na_(2) S_(2) O_(2)`
Thus `O_(2)` is an oxidant
`2Ag (CN)_(2)^(-) +Zn rarr [ Zn (CN)_(4)]^(2-)+ 2Ag darr`
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