`BaSO_4` is ionic and `PCl_3` is covalent but a saturated solution of `BaSO_4` is a weak electrolyte, while that the `PCl_3` is a strong electrolyte. Explain.
`BaSO_4` is ionic and `PCl_3` is covalent but a saturated solution of `BaSO_4` is a weak electrolyte, while that the `PCl_3` is a strong electrolyte. Explain.
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To explain why BaSO₄ is a weak electrolyte despite being ionic, while PCl₃ is a strong electrolyte despite being covalent, we can break down the reasoning into several steps.
### Step-by-Step Solution:
1. **Understanding Ionic Compounds**:
- BaSO₄ (Barium Sulfate) is an ionic compound, which means it is composed of ions held together by strong electrostatic forces (ionic bonds).
- Ionic compounds typically dissociate into their constituent ions when dissolved in water, which allows them to conduct electricity.
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A solution which remains in equilibrium with undissolved solute , in contact , is said to be saturated . The concentration of a saturated solution at a given temperature is a called solubility . The product of concentration of ions in a saturated solution of an electrolyte at a given temperature is called solubility product (K_(sp)) . For the electrolyte A_(x),B_(y) with solubility S. The solubility product (K_(sp)) is given as K_(sp) = x^(x) xx y^(y) xx S^(x-y) . While calculating the solubility of a sparingly . soluable salt in the presence of some strong electrolyte containing a common ion , the common ion concentration is practically equal to that of strong electrolyte containing a common ion . the common ion soncentration is practically equal to that of strong electrolyte . If in a solution , the ionic product of an electroylte exceeds its K_(sp) value at a particular temperature , then precipitation occurs . If two or more electrolyte are presentt in the solution , then by the addition of some suitable reagent , precipitation generally occurs in increasing order of their k_(sp) values . Solubility of some sparingly soluable salts , is sometimes enhanced through complexation . While we are calculating the solubility of some sparingly or pH of an electrolyte , the nature of cation of anion should be checked carefully whether there ion (s) are capable of undergoing hydrolysis or not . If either or both of the ions are capable of undergoing hydrolysis , it should be taken into account in calculating the solubility . While calculating the pH of an amphiprotic species , it should be checked whether or not cation can undergo hydrolysis . Total a_(H^(-)) = sqrt(K_(a_(1)xxK_(a_(2)))) (if cation do not undergo hydrolysis ) a_(H^(+)) = sqrt(K_(a_(1))((K_(w))/(K_(b)) - K_(a_(2)))) (if cation also undergoes hydrolysis ) where symbols have usual meaning . Solubility of solids into liquids is a function of temperature alone but solubility of gases into liquids is a function of temperature as well as pressure . The effect of pressure on solubility of gases into liquids is governed by Henry's law . The solubility of BaSO_(4) in 0.1 M BaCl_(2) solution is (K_(sp) " of " BaSO_(4) = 1.5 xx 10^(-9))
A solution which remains in equilibrium with undissolved solute is said to be saturated. The concentration of a saturated solution at a given temperature is called solubility. The product of concentration of ions in a saturated solution of an electrolyte at a given temperature, is called solubility product (K_(sp)) . For the electrolyte, A_(x),B_(y),:A_(x),B_(y(s)) rarr xA^(y+)+ y^(Bx-) , with solubility S, the solubility product (K_(sp)) =x^(x)xxy^(y) xx s^(x+y) . While calculating the solubility of a sparingly soluble salt in the presence of some strong electrolyte containing a common ion, the common ion concentration is practically equal to that of strong electrolyte. If in a solution, the ionic product of an clectrolyte exceeds its K_(sp) , value at a particular temperature, then precipitation occurs. The solubility of BaSO_(4) , in 0.1 M BaCl_(2) , solution is (K_(sp) , of BaSO_(4), = 1.5 xx 10^(-9))
State why an aq. solution of NH_(3) i] turns red litmus blue ii] is a weak base and a weak electrolyte.
A solution which remains in equilibrium with undissolved solute is said to be saturated. The concentration of a saturated solution at a given temperature is called solubility. The product of concentration of ions in a saturated solution of an electrolyte at a given temperature, is called solubility product (K_(sp)) . For the electrolyte, A_(x),B_(y),:A_(x),B_(y(s)) rarr xA^(y+)+ y^(Bx-) , with solubility S, the solubility product (K_(sp)) =x^(x)xxy^(y) xx s^(x+y) . While calculating the solubility of a sparingly soluble salt in the presence of some strong electrolyte containing a common ion, the common ion concentration is practically equal to that of strong electrolyte. If in a solution, the ionic product of an clectrolyte exceeds its K_(sp) , value at a particular temperature, then precipitation occurs. The solubility of PbSO_(4) , in water is 0.303 g/l at 25^(@) C, its solubility product at that temperature is
A solution which remains in equilibrium with undissolved solute is said to be saturated. The concentration of a saturated solution at a given temperature is called solubility. The product of concentration of ions in a saturated solution of an electrolyte at a given temperature, is called solubility product (K_(sp)) . For the electrolyte, A_(x),B_(y),:A_(x),B_(y(s)) rarr xA^(y+)+ y^(Bx-) , with solubility S, the solubility product (K_(sp)) =x^(x)xxy^(y) xx s^(x+y) . While calculating the solubility of a sparingly soluble salt in the presence of some strong electrolyte containing a common ion, the common ion concentration is practically equal to that of strong electrolyte. If in a solution, the ionic product of an clectrolyte exceeds its K_(sp) , value at a particular temperature, then precipitation occurs. The solubility of PbSO_(4) , in water is 0.303 g/l at 25^(@) C, its solubility at that temperature is
Describe the characteristics of variation of molar conductivity with dilution for : (a) a weak electrolyte (b) a strong electrolyte How are these explained qualitatively?
To obeserve the effect of concentration on the conductivity, electrolytes of different natures are taken in two vessels A and B, A contains weak electrolyte, e.g., NH_(4)OH and B contains strong electrolyte, e.g., NaCl . In both containers, the concentration of respective electrolyte is increased and the conductivity observed :
To obeserve the effect of concentration on the conductivity, electrolytes of different natures are taken in two vessels A and B, A contains weak electrolyte, e.g., NH_(4)OH and B contains strong electrolyte, e.g., NaCl . In both containers, the concentration of respective electrolyte is increased and the conductivity observed :
Let C_(NaCl) and C_(BaSO_(4)) be the conductances (in S) measured for saturated aqueous solutions of NaCl and BaSO4, respectively, at a temperature T. Which of the following is false?
Account for the following BiCl_3 is less covalent than PCl_3 .
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