Home
Class 12
CHEMISTRY
How many hours are needed to deposit the...

How many hours are needed to deposit the metal based on the reaction .
`Fe^(2+)(aq) + 2e^(-) to Fe(s)`. using a current strength of 0.02amp.

Text Solution

AI Generated Solution

The correct Answer is:
To determine how many hours are needed to deposit iron using the given reaction and current strength, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is: \[ \text{Fe}^{2+}(aq) + 2e^{-} \rightarrow \text{Fe}(s) \] This indicates that 1 mole of Fe is deposited by the transfer of 2 moles of electrons. 2. **Determine the Equivalent Weight of Iron**: The molar mass of iron (Fe) is 56 g/mol. Since iron has a +2 charge in this reaction, the equivalent weight (E) is calculated as: \[ E = \frac{\text{Molar Mass}}{\text{n}} = \frac{56 \text{ g/mol}}{2} = 28 \text{ g/equiv} \] 3. **Use Faraday's First Law of Electrolysis**: According to Faraday's first law, the weight of the substance deposited (W) is given by: \[ W = \frac{E \cdot I \cdot T}{F} \] where: - \( W \) = weight of the substance (in grams) - \( E \) = equivalent weight (in grams/equiv) - \( I \) = current (in amperes) - \( T \) = time (in seconds) - \( F \) = Faraday's constant (approximately 96500 C/equiv) 4. **Rearranging the Formula**: We need to find the time \( T \). Rearranging the formula gives: \[ T = \frac{W \cdot F}{E \cdot I} \] 5. **Substituting Values**: Here, we want to deposit 1 mole of iron, which corresponds to 28 g (the equivalent weight we calculated). Now substituting the values: \[ T = \frac{28 \text{ g} \cdot 96500 \text{ C/equiv}}{28 \text{ g/equiv} \cdot 0.02 \text{ A}} \] 6. **Simplifying the Equation**: The 28 g cancels out: \[ T = \frac{96500}{0.02} \] \[ T = 4825000 \text{ seconds} \] 7. **Convert Seconds to Hours**: To convert seconds into hours, divide by 3600 (the number of seconds in an hour): \[ T_{\text{hours}} = \frac{4825000}{3600} \approx 1340.28 \text{ hours} \] ### Final Answer: Approximately **1340.28 hours** are needed to deposit the metal.
Promotional Banner

Similar Questions

Explore conceptually related problems

For the reaction Fe_2N(s)+(3)/(2)H_2(g)=2Fe(s)+NH_3(g)

How many hours does it take to reduce 3 moles of Fe^(3+) to Fe^(2+) with 2A current intensity ?

What is ‘A’ in the following reaction? 2Fe^(3+) (aq) + Sn^(2+) (aq) rarr 2 Fe^(2+) (aq) + A

what is the emf at 25^(@)C for the cell, Ag|{:(AgBr(s)" " Br^(-)), (" "alpha = 0.34):}||{:(Fe^(3+) " " Fe^(2+)), (alpha = 0.1 " " alpha = 0.02):}|Pt The standard reduction potentials for the half-reactions AgBr + e^(-) rightarrow Ag + Br^(-) and Fe^(3+) + e^(-) rightarrow Fe^(2+) are +0.0713V and +0.770V respectively.

How many of these metals carbon reduction is used during their extraction. Ag, Au, Fe, Sn, Zn, Pb, Al

Consider the following E^(@) values E^(@) values E_(Fe^(3+)//Fe^(2+))^(@)= 0.77v , E_(Sn^(2+)//Sn)^(@) = -0.14 under standard condition the potential for the reaction Sn_(s)+ 2Fe^(3+)(aq)rightarrow 2Fe^(2+)(aq) + Sn^(2+) (aq) is :

Standard oxidation potential for the following half-cell reactions are [Fe(s) rarr Fe^(2+)(aq) + 2e^(-) E^3 = +0.44 V] [Co(s)rarr Co^(3+) (aq) + 3e^(-) E^0 = - 1.81 V The standard emf of the cell reaction [3Fe(s) +2Co^(3+) (aq)rarr 3Fe^(2+) (aq) + 2Co(s)] , will be

E^(o) for the reaction Fe + Zn^(2+) rarr Zn + Fe^(2+) is – 0.35 V. The given cell reaction is :

Calculate the standard cell potential (in V) of the cell in which following reaction takes place: Fe ^( 2 + ) ( aq ) + A g^ + ( aq ) to Fe ^( 3 + ) ( aq ) + Ag (s ) Given that E _ (Ag ^ + // Ag ) ^ 0 = x V , E _ ( Fe^( 2+ ) // Fe ) ^0 = yV , E _ (Fe^(3+)//F e )^0 = z V

Write the equilibrium constant expression for the following reactions : Fe^(3+) (aq) + SCN^(-) (aq) hArr FeSCN^(2+) (aq)