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One normal salt solution surrounding two...

One normal salt solution surrounding two platinum electrodes, 2.1 cm apart and `6.3 cm^(2)` in area was found to offer a resistance of 50 ohm. Calculate the equivalent conductivity solution.

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To calculate the equivalent conductivity of the salt solution, we will follow these steps: ### Step 1: Identify the given values - Distance between electrodes (l) = 2.1 cm - Area of electrodes (A) = 6.3 cm² - Resistance (R) = 50 ohms ### Step 2: Convert the distance to meters Since conductivity is usually expressed in SI units, we convert the distance from centimeters to meters. - \( l = 2.1 \, \text{cm} = 0.021 \, \text{m} \) ### Step 3: Calculate the specific conductance (k) The formula for specific conductance (k) is given by: \[ k = \frac{l}{A} \times \frac{1}{R} \] Substituting the values: \[ k = \frac{0.021 \, \text{m}}{6.3 \, \text{cm}^2} \times \frac{1}{50 \, \Omega} \] Note: Convert area from cm² to m²: \[ A = 6.3 \, \text{cm}^2 = 6.3 \times 10^{-4} \, \text{m}^2 \] Now substituting: \[ k = \frac{0.021}{6.3 \times 10^{-4}} \times \frac{1}{50} \] ### Step 4: Calculate the specific conductance value Calculating the above expression: \[ k = \frac{0.021}{0.00063} \times \frac{1}{50} \] \[ k = 33.33 \times \frac{1}{50} = 0.6666 \, \text{S/m} \] ### Step 5: Convert specific conductance to equivalent conductivity The equivalent conductivity (Λ) is given by: \[ \Lambda = k \times V \] Where V is the volume of the solution. Since we have a 1 normal solution, we assume the volume (V) to be 1 liter (1000 mL). \[ \Lambda = 0.6666 \, \text{S/m} \times 1 \, \text{L} = 0.6666 \, \text{S m}^2/\text{mol} \] ### Step 6: Convert to appropriate units Convert S/m to ohm⁻¹ cm⁻¹: \[ 0.6666 \, \text{S/m} = 0.06666 \, \text{ohm}^{-1} \, \text{cm}^{-1} \] Thus, \[ \Lambda = 0.06666 \, \text{ohm}^{-1} \, \text{cm}^{-1} \times 1000 = 66.66 \, \text{ohm}^{-1} \, \text{cm}^{-1} \] ### Final Answer The equivalent conductivity of the solution is approximately: \[ \Lambda \approx 66.66 \, \text{ohm}^{-1} \, \text{cm}^{-1} \]
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