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Degree of dissociation of decinormal ace...

Degree of dissociation of decinormal acetic acid is `3.66% ` at `25^@C`.If the equivalent conductance at infinite dilution of acetic acid at `25^@C` is `390.7 "ohm"^(-1)`,calculate the equivalent conductance at given concentration.

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To solve the problem, we need to calculate the equivalent conductance at the given concentration of acetic acid using the degree of dissociation and the equivalent conductance at infinite dilution. ### Step-by-Step Solution: 1. **Identify Given Values:** - Degree of dissociation (α) = 3.66% = 0.0366 (as a decimal) - Equivalent conductance at infinite dilution (λ₀) = 390.7 ohm⁻¹ cm² equiv⁻¹ 2. **Use the Formula for Equivalent Conductance:** The relationship between the degree of dissociation (α), equivalent conductance at a given concentration (λ), and equivalent conductance at infinite dilution (λ₀) is given by: \[ \alpha = \frac{\lambda}{\lambda_0} \] 3. **Rearranging the Formula:** We can rearrange the formula to find the equivalent conductance (λ) at the given concentration: \[ \lambda = \alpha \cdot \lambda_0 \] 4. **Substitute the Values:** Now, substitute the known values into the equation: \[ \lambda = 0.0366 \cdot 390.7 \] 5. **Calculate λ:** Performing the multiplication: \[ \lambda = 0.0366 \times 390.7 \approx 14.299 \, \text{ohm}^{-1} \, \text{cm}^2 \, \text{equiv}^{-1} \] 6. **Final Answer:** The equivalent conductance at the given concentration of acetic acid is approximately: \[ \lambda \approx 14.299 \, \text{ohm}^{-1} \, \text{cm}^2 \, \text{equiv}^{-1} \]
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