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2Na(2)S(2)O(3)+I(2)toNa(2)S(4)O(6)+2NaI ...

`2Na_(2)S_(2)O_(3)+I_(2)toNa_(2)S_(4)O_(6)+2NaI`
How many equivalents of Hypo is oxidised by one mole of Iodine?

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To determine how many equivalents of sodium thiosulfate (hypo, Na2S2O3) are oxidized by one mole of iodine (I2), we can follow these steps: ### Step 1: Write the Balanced Chemical Equation The balanced chemical equation given is: \[ 2 \text{Na}_2\text{S}_2\text{O}_3 + \text{I}_2 \rightarrow \text{Na}_2\text{S}_4\text{O}_6 + 2 \text{NaI} \] ### Step 2: Identify the Oxidation States In sodium thiosulfate (Na2S2O3), the oxidation state of sulfur is +2. In the product sodium tetrathionate (Na2S4O6), the oxidation state of sulfur is +2.5. This indicates that sulfur is being oxidized. ### Step 3: Calculate the Change in Oxidation State The change in oxidation state for sulfur can be calculated as follows: - Initial oxidation state of sulfur in Na2S2O3 = +2 - Final oxidation state of sulfur in Na2S4O6 = +2.5 The change in oxidation state per sulfur atom is: \[ +2.5 - +2 = +0.5 \] ### Step 4: Determine the N Factor The n-factor for the reaction can be calculated based on the change in oxidation state: - Since there are 2 moles of Na2S2O3, the total change for 2 moles of sulfur is: \[ 2 \text{ moles} \times 0.5 = 1 \text{ equivalent} \] ### Step 5: Relate Iodine to Sodium Thiosulfate From the balanced equation, we see that 1 mole of I2 reacts with 2 moles of Na2S2O3. Therefore, for 1 mole of iodine, the equivalents of sodium thiosulfate oxidized can be calculated as follows: - 1 mole of I2 oxidizes 2 equivalents of Na2S2O3. ### Conclusion Thus, **2 equivalents of sodium thiosulfate (hypo) are oxidized by one mole of iodine (I2)**. ---
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