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One gram limestone is heated and quickli...

One gram limestone is heated and quickline so formed is dissolved in one litre of water. The normality of solution is `0.01 xx x`.What is value of x.

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To solve the problem step-by-step, we will follow the chemical reactions and calculations involved in the process of heating limestone and dissolving quicklime in water. ### Step 1: Understand the Reaction When limestone (calcium carbonate, CaCO₃) is heated, it decomposes into quicklime (calcium oxide, CaO) and carbon dioxide (CO₂): \[ \text{CaCO}_3 (s) \rightarrow \text{CaO} (s) + \text{CO}_2 (g) \] ### Step 2: Calculate the Molar Mass of Calcium Carbonate (CaCO₃) The molar mass of calcium carbonate is calculated as follows: - Calcium (Ca) = 40 g/mol - Carbon (C) = 12 g/mol - Oxygen (O) = 16 g/mol (and there are 3 oxygen atoms) Thus, the molar mass of CaCO₃: \[ \text{Molar mass of CaCO}_3 = 40 + 12 + (16 \times 3) = 100 \text{ g/mol} \] ### Step 3: Calculate the Molar Mass of Calcium Oxide (CaO) The molar mass of calcium oxide is: - Calcium (Ca) = 40 g/mol - Oxygen (O) = 16 g/mol Thus, the molar mass of CaO: \[ \text{Molar mass of CaO} = 40 + 16 = 56 \text{ g/mol} \] ### Step 4: Determine the Amount of Quicklime Produced From the reaction, 100 g of CaCO₃ produces 56 g of CaO. Therefore, if we start with 1 g of CaCO₃: \[ \text{Quicklime produced} = \left(\frac{56 \text{ g CaO}}{100 \text{ g CaCO}_3}\right) \times 1 \text{ g CaCO}_3 = 0.56 \text{ g CaO} \] ### Step 5: Calculate the Equivalent Mass of Calcium Oxide (CaO) The equivalent mass of a substance is calculated as: \[ \text{Equivalent mass} = \frac{\text{Molar mass}}{n} \] where \( n \) is the number of equivalents. For CaO, since it can provide 2 moles of hydroxide ions (OH⁻) when dissolved in water, the \( n \) factor is 2: \[ \text{Equivalent mass of CaO} = \frac{56 \text{ g/mol}}{2} = 28 \text{ g/equiv} \] ### Step 6: Calculate the Number of Equivalents of CaO The number of equivalents is given by: \[ \text{Number of equivalents} = \frac{\text{Given mass}}{\text{Equivalent mass}} \] Using the mass of quicklime produced: \[ \text{Number of equivalents} = \frac{0.56 \text{ g}}{28 \text{ g/equiv}} = 0.02 \text{ equiv} \] ### Step 7: Calculate the Normality of the Solution Normality (N) is defined as the number of equivalents per liter of solution: \[ \text{Normality} = \frac{\text{Number of equivalents}}{\text{Volume of solution in liters}} \] Since the volume of the solution is 1 liter: \[ \text{Normality} = 0.02 \text{ equiv} / 1 \text{ L} = 0.02 \text{ N} \] ### Step 8: Relate Normality to the Given Expression According to the problem, the normality of the solution is given as: \[ 0.01 \times x \] Setting this equal to the calculated normality: \[ 0.01 \times x = 0.02 \] ### Step 9: Solve for x To find the value of \( x \): \[ x = \frac{0.02}{0.01} = 2 \] ### Final Answer The value of \( x \) is **2**. ---
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