Home
Class 12
CHEMISTRY
Real gases exert less pressure when comp...

Real gases exert less pressure when compared with ideal gases due to the attraction between the gas molecules. Reduction in pressure of real gases `prop` `("Concentration of gas")^(n)`. What is the value of n ?

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the value of \( n \) in the relationship that describes how the reduction in pressure of real gases is proportional to the concentration of gas raised to the power of \( n \). ### Step-by-Step Solution: 1. **Understanding Real Gases vs. Ideal Gases**: - Real gases exert less pressure compared to ideal gases due to intermolecular attractions. In ideal gases, these attractions are negligible. 2. **Using the Van der Waals Equation**: - The Van der Waals equation for \( n \) moles of a real gas is given by: \[ \left( p + \frac{a n^2}{V^2} \right)(V - nb) = nRT \] - Here, \( a \) and \( b \) are Van der Waals constants specific to each gas. 3. **Identifying Pressure Correction**: - The term \( \frac{a n^2}{V^2} \) represents the pressure correction due to intermolecular forces. This indicates that the actual pressure \( p \) is reduced by this term. 4. **Relating Concentration to Pressure Reduction**: - The concentration \( c \) of the gas can be expressed as: \[ c = \frac{n}{V} \] - Therefore, we can express the pressure reduction in terms of concentration. 5. **Finding the Relationship**: - The reduction in pressure \( \Delta p \) can be expressed as being proportional to the pressure correction term: \[ \Delta p \propto \frac{a n^2}{V^2} \] - Substituting \( c \) into this equation gives: \[ \Delta p \propto \frac{a c^2}{V^2} \] - Since \( c = \frac{n}{V} \), we can rewrite this as: \[ \Delta p \propto c^2 \] 6. **Conclusion**: - From the above relationship, we see that the reduction in pressure of real gases is directly proportional to the concentration squared. Therefore, the value of \( n \) is: \[ n = 2 \] ### Final Answer: The value of \( n \) is \( 2 \).
Promotional Banner

Similar Questions

Explore conceptually related problems

The pressure exerted by real gas is :-

Gases deviate from the ideal gas behaviour because their molecules

In the corrections made to the ideal gas equation for real gases, the reduction in pressure due to attractive forces is directly proportional to :

Real gases do not obey ideal gas equation,

Write down the gas equation applicable to real gases.

The most ideal gas among real gases is

The pressure of real gas is less than the pressure of an ideal gas because of

The observed pressure of real gas is more than the ideal pressure.

The kinetic theory of gases presumes the collisions between the molecules to be perfectly elastic because the collisions between molecules of a gas:

Assertion : The pressure of real gas is less than the pressure of ideal gas. Reason : Intermolecular forces of attraction in real gases are greater than in ideal gas.