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Choose the wrong statement

A

The corrected pressure `P + (an^(2))/V^(2)` in Vander Waals equation (symbols have their usual meanings) is the pressure which the gas would exert if it were ideal

B

Above their respective Boyle's temperatures, `H_(2)` shows positive deviation throughout (`z gt 1`) while `O_(2)` shows negative deviation (`z lt 1`) followed by positive deviation (z `gt` 1)

C

A gas shows negative deviation when long range attractive intermolecular forces are dominating

D

The intercept of PV vs P isotherm of any gas at 27°C is equal to 24.4 L atm `"mol"^(-1)`

Text Solution

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The correct Answer is:
B
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