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{:(List - I , List - II),((A) N(2) + O(2...

`{:(List - I , List - II),((A) N_(2) + O_(2) hArr 2NO,(P) (atm)^(-2)),((B) 2SO_(2)(g) + O_(2) hArr 2SO_(3)(g),(Q) "No unit"),((C) H_(2) + I_(2) hArr 2HI,(R)"No cffect of pressure"),((D) N_(2)(g) + 3H_(2) (g) hArr 2NH_(3)(g), (S) "High pressure favours forward reaction"):}`

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The correct Answer is:
To solve the given problem, we need to match the reactions from List I with their corresponding effects or characteristics from List II. Let's analyze each reaction step by step. ### Step 1: Analyze Reaction A **Reaction:** \( N_2 + O_2 \rightleftharpoons 2NO \) - **Moles of Reactants:** 2 (1 mole of \( N_2 \) + 1 mole of \( O_2 \)) - **Moles of Products:** 2 (2 moles of \( NO \)) - **Effect of Pressure:** Since the number of moles of reactants equals the number of moles of products, there is no change in volume when pressure is applied. Therefore, there is **no effect of pressure**. - **Unit of Equilibrium Constant (K):** Since the number of moles is the same on both sides, the equilibrium constant has **no unit**. **Conclusion for A:** Matches with (Q) "No unit" and (R) "No effect of pressure". ### Step 2: Analyze Reaction B **Reaction:** \( 2SO_2(g) + O_2 \rightleftharpoons 2SO_3(g) \) - **Moles of Reactants:** 3 (2 moles of \( SO_2 \) + 1 mole of \( O_2 \)) - **Moles of Products:** 2 (2 moles of \( SO_3 \)) - **Effect of Pressure:** Since the number of moles decreases from 3 to 2, increasing pressure will favor the forward reaction (towards fewer moles). - **Unit of Equilibrium Constant (K):** The equilibrium constant will have units of \( atm^{-1} \) due to the change in moles. **Conclusion for B:** Matches with (S) "High pressure favors forward reaction". ### Step 3: Analyze Reaction C **Reaction:** \( H_2 + I_2 \rightleftharpoons 2HI \) - **Moles of Reactants:** 2 (1 mole of \( H_2 \) + 1 mole of \( I_2 \)) - **Moles of Products:** 2 (2 moles of \( HI \)) - **Effect of Pressure:** Similar to Reaction A, since the number of moles is the same on both sides, there is **no effect of pressure**. - **Unit of Equilibrium Constant (K):** The equilibrium constant has **no unit**. **Conclusion for C:** Matches with (Q) "No unit" and (R) "No effect of pressure". ### Step 4: Analyze Reaction D **Reaction:** \( N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g) \) - **Moles of Reactants:** 4 (1 mole of \( N_2 \) + 3 moles of \( H_2 \)) - **Moles of Products:** 2 (2 moles of \( NH_3 \)) - **Effect of Pressure:** Since the number of moles decreases from 4 to 2, increasing pressure will favor the forward reaction (towards fewer moles). - **Unit of Equilibrium Constant (K):** The equilibrium constant will have units of \( atm^{-2} \) due to the change in moles. **Conclusion for D:** Matches with (P) \( (atm)^{-2} \) and (S) "High pressure favors forward reaction". ### Final Matching: - A: (Q) "No unit", (R) "No effect of pressure" - B: (S) "High pressure favors forward reaction" - C: (Q) "No unit", (R) "No effect of pressure" - D: (P) \( (atm)^{-2} \), (S) "High pressure favors forward reaction" ### Summary of Answers: - A → Q, R - B → S - C → Q, R - D → P, S
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