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For 2 SO(2) + O(2) hArr 2SO(3). Delta H...

For `2 SO_(2) + O_(2) hArr 2SO_(3). Delta ` H = - Q KJ. as per Lechatelier's principle which of the following changes favours forward reaction, yielding more `SO_(3)`
(A) Adding more `O_(2) " "`(B) Removing `SO_(3)" "`(C) Applying high P `" "` (D) Change of catalyst

A

A, B, C & D

B

A, B & D

C

A & D

D

A, B & C

Text Solution

AI Generated Solution

The correct Answer is:
To determine which changes favor the forward reaction \(2 SO_2 + O_2 \rightleftharpoons 2 SO_3\) according to Le Chatelier's principle, we will analyze each option step by step. ### Step 1: Understand the Reaction The given reaction is: \[ 2 SO_2 + O_2 \rightleftharpoons 2 SO_3 \] This reaction is exothermic, as indicated by \(\Delta H = -Q\) (heat is released). ### Step 2: Analyze Each Option #### Option A: Adding More \(O_2\) - **Effect**: According to Le Chatelier's principle, adding more reactants shifts the equilibrium to the right (forward reaction) to produce more products. - **Conclusion**: This change favors the formation of \(SO_3\). #### Option B: Removing \(SO_3\) - **Effect**: Removing a product will also shift the equilibrium to the right to replace the removed product. - **Conclusion**: This change favors the formation of \(SO_3\). #### Option C: Applying High Pressure - **Effect**: Increasing the pressure favors the side of the reaction with fewer moles of gas. In this case, the left side has 3 moles (2 from \(SO_2\) and 1 from \(O_2\)) and the right side has 2 moles (\(2 SO_3\)). Therefore, increasing pressure will shift the equilibrium to the right. - **Conclusion**: This change favors the formation of \(SO_3\). #### Option D: Change of Catalyst - **Effect**: A catalyst speeds up both the forward and reverse reactions equally but does not change the position of equilibrium. - **Conclusion**: This change does not favor the formation of \(SO_3\). ### Final Conclusion The changes that favor the forward reaction yielding more \(SO_3\) are: - **Option A**: Adding more \(O_2\) - **Option B**: Removing \(SO_3\) - **Option C**: Applying high pressure **Correct Options**: A, B, and C.
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