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Give the relation between Kc and Delta G...

Give the relation between Kc and Delta G

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To establish the relationship between the equilibrium constant (Kc) and the change in Gibbs free energy (ΔG), we can follow these steps: ### Step 1: Understand the Definitions - **Kc**: The equilibrium constant for a reaction at equilibrium, expressed in terms of the concentrations of the products and reactants. - **ΔG**: The change in Gibbs free energy, which indicates the spontaneity of a reaction. A negative ΔG suggests that the reaction is spontaneous. ### Step 2: Write the Fundamental Equation The relationship between ΔG and Kc is given by the equation: \[ \Delta G^\circ = -RT \ln K_c \] Where: - \( \Delta G^\circ \) is the standard change in Gibbs free energy. - \( R \) is the universal gas constant (approximately 8.314 J/(mol·K)). - \( T \) is the absolute temperature in Kelvin. - \( K_c \) is the equilibrium constant. ### Step 3: Analyze the Equation - The equation shows that ΔG is directly related to the natural logarithm of Kc. - If Kc > 1, then ΔG < 0 (the reaction is spontaneous). - If Kc < 1, then ΔG > 0 (the reaction is non-spontaneous). - If Kc = 1, then ΔG = 0 (the system is at equilibrium). ### Step 4: Conclusion Thus, the relationship between Kc and ΔG can be summarized as: - A larger Kc indicates a more favorable reaction (more products at equilibrium), resulting in a more negative ΔG. - Conversely, a smaller Kc indicates a less favorable reaction (more reactants at equilibrium), resulting in a more positive ΔG. ### Final Relation The final relation can be expressed as: \[ \Delta G^\circ = -RT \ln K_c \] ---
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