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Which statement(s) is correct,...

Which statement(s) is correct,

A

`((delta H)/(delta T))_(P) - ((deltaU)/(deltaT))_(V) = R`

B

`((deltaH)/(deltaT))_(P) gt ((deltaU)/(deltaT))_(V)`

C

`((deltaH)/(deltaV))_(T)` for ideal gas is zero

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding which statements are correct, we will analyze each statement based on the principles of thermodynamics. ### Step-by-Step Solution: 1. **Understanding Enthalpy and Internal Energy**: - We start with the definitions: - Change in enthalpy (\( \Delta H \)) at constant pressure is given by: \[ \Delta H = C_p \Delta T \] - Change in internal energy (\( \Delta U \)) at constant volume is given by: \[ \Delta U = C_v \Delta T \] 2. **Relating \( C_p \) and \( C_v \)**: - The relationship between the heat capacities for an ideal gas is: \[ C_p - C_v = R \] - This shows that the difference between the heat capacities at constant pressure and constant volume equals the universal gas constant \( R \). 3. **Analyzing the First Statement**: - The first statement claims: \[ \frac{\Delta H}{\Delta T} \text{ at constant pressure} - \frac{\Delta U}{\Delta T} \text{ at constant volume} = C_p - C_v \] - From our earlier relationship, we can conclude that this is correct because: \[ C_p - C_v = R \] 4. **Analyzing the Second Statement**: - The second statement claims: \[ \frac{\Delta H}{\Delta T} \text{ at constant pressure} - \frac{\Delta U}{\Delta T} \text{ at constant volume} > 0 \] - Since \( C_p - C_v = R \) and \( R > 0 \) for an ideal gas, this statement is also correct. 5. **Analyzing the Third Statement**: - The third statement claims that: \[ \frac{\Delta H}{\Delta V} \text{ at constant temperature} = 0 \] - For an ideal gas, we know that: \[ H = U + PV = U + RT \] - Since internal energy \( U \) is a function of temperature only, at constant temperature, \( \Delta U \) does not change with volume. Thus: \[ \frac{\Delta H}{\Delta V} = 0 + R \frac{\Delta T}{\Delta V} = 0 \] - Therefore, this statement is also correct. 6. **Conclusion**: - Since all three statements are correct, the final conclusion is that the correct option is "All of the above."
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