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Which of following is correct ?...

Which of following is correct ?

A

Reversible adiabatic process is isoentropic

B

`Delta S_(sys)` for irreversible adiabatic compression is greater than zero

C

`Delta S_(sys)` for free expansion is zero

D

`Delta S_(sys)` for irreversible isothermal compression is greater than zero

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given statements about thermodynamic processes are correct, let's analyze each statement step by step: ### Step 1: Analyze Statement 1 **Statement 1:** "Reversible adiabatic process is isoentropic." - An adiabatic process is one in which no heat is exchanged with the surroundings (Q = 0). - A reversible adiabatic process is indeed isoentropic, meaning the entropy of the system remains constant throughout the process. - Therefore, **Statement 1 is correct.** ### Step 2: Analyze Statement 2 **Statement 2:** "ΔS system for irreversible adiabatic compression is greater than 0." - For an irreversible adiabatic process, while the heat exchange (Q) is still 0, the change in entropy (ΔS) can be calculated using the relationship ΔS = Q/T. - However, since the process is irreversible, the entropy of the system will increase due to the irreversibility, even though Q = 0. - Hence, ΔS system for irreversible adiabatic compression is indeed greater than 0. - Therefore, **Statement 2 is correct.** ### Step 3: Analyze Statement 3 **Statement 3:** "ΔS system for free expansion is 0." - In a free expansion, a gas expands into a vacuum without doing work and without heat exchange (Q = 0). - However, the entropy of the system does increase because the gas occupies a larger volume and has more microstates available. - Thus, ΔS system for free expansion is not 0; it is greater than 0. - Therefore, **Statement 3 is incorrect.** ### Step 4: Analyze Statement 4 **Statement 4:** "ΔS system for irreversible isothermal compression is greater than 0." - In an isothermal process, the temperature remains constant, and for an irreversible process, the system does not reach equilibrium. - Even though the system is compressing and work is being done, heat is still exchanged with the surroundings. - The change in entropy for an irreversible isothermal process is greater than 0 because the system is not in equilibrium and the process is irreversible. - Therefore, **Statement 4 is correct.** ### Conclusion After analyzing all statements, we find that: - **Correct Statements:** 1, 2, and 4 - **Incorrect Statement:** 3 ### Final Answer The correct options are 1, 2, and 4. ---
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