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For an ideal monoatomic gas during any p...

For an ideal monoatomic gas during any process T=kV, find out the molar heat capacity of the gas during the process. (Assume vibrational degree of freedom to be active)

A

`(5)/(2)R`

B

3R

C

`(7)/(2)`R

D

4R

Text Solution

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The correct Answer is:
To solve the problem of finding the molar heat capacity of an ideal monoatomic gas during a process where \( T = kV \) (with \( k \) being a constant), we will follow these steps: ### Step 1: Understand the relationship between temperature and volume Given that \( T = kV \), we can infer that temperature \( T \) is directly proportional to volume \( V \). This implies that as the volume changes, the temperature also changes proportionally. **Hint:** Identify how changes in one variable affect another in thermodynamic processes. ### Step 2: Analyze the implications for pressure From the ideal gas law, we know that for an ideal gas: \[ PV = nRT \] Substituting \( T = kV \) into the equation gives: \[ P = \frac{nR(kV)}{V} = nkR \] This indicates that the pressure \( P \) is constant because \( k \) is a constant and does not depend on \( V \). **Hint:** Use the ideal gas law to relate pressure, volume, and temperature. ### Step 3: Determine the molar heat capacity at constant pressure For an ideal monoatomic gas, the molar heat capacity at constant pressure \( C_P \) is given by: \[ C_P = \frac{5}{2}R \] This value comes from the degrees of freedom of a monoatomic gas, which includes 3 translational and 2 rotational degrees of freedom (and we assume vibrational degrees of freedom are active). **Hint:** Recall the formula for molar heat capacity based on the degrees of freedom of the gas. ### Step 4: Conclude the molar heat capacity during the process Since we established that the pressure is constant during the process (as derived from the relationship \( T = kV \)), the molar heat capacity of the gas during this process will be equal to the molar heat capacity at constant pressure: \[ C = C_P = \frac{5}{2}R \] **Hint:** Relate the conditions of the process to known heat capacity values. ### Final Answer Thus, the molar heat capacity of the ideal monoatomic gas during the process where \( T = kV \) is: \[ C = \frac{5}{2}R \]
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