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At some high temperature, K(w) of water ...

At some high temperature, `K_(w)` of water is `10^(-13)` Then the `P^(H)` of the water at the same temperature is

A

`7.0`

B

`6.5`

C

`7.5`

D

`7.23`

Text Solution

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The correct Answer is:
To find the pH of water at a high temperature where the ionic product of water (Kw) is \(10^{-13}\), we can follow these steps: ### Step 1: Understand the Ionic Product of Water The ionic product of water (\(K_w\)) is defined as: \[ K_w = [H^+][OH^-] \] For pure water, the concentration of hydrogen ions \([H^+]\) is equal to the concentration of hydroxide ions \([OH^-]\). ### Step 2: Set Up the Equation Since \([H^+] = [OH^-]\) in pure water, we can express \(K_w\) as: \[ K_w = [H^+]^2 \] ### Step 3: Substitute the Given Value of \(K_w\) From the question, we know that: \[ K_w = 10^{-13} \] Thus, we can write: \[ [H^+]^2 = 10^{-13} \] ### Step 4: Solve for \([H^+]\) To find \([H^+]\), we take the square root of both sides: \[ [H^+] = \sqrt{10^{-13}} = 10^{-6.5} \] ### Step 5: Calculate the pH The pH is calculated using the formula: \[ pH = -\log[H^+] \] Substituting the value of \([H^+]\): \[ pH = -\log(10^{-6.5}) = 6.5 \] ### Conclusion Therefore, the pH of water at this high temperature is: \[ \text{pH} = 6.5 \]
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