Home
Class 12
CHEMISTRY
0.01M CH(3),COOH is 4.24% ionised. What ...

0.01M `CH_(3),COOH` is 4.24% ionised. What will be the pereentage ionisation of 0.1 `M CH_(3),COOH.`

A

`1.34%`

B

`4.23%`

C

`5.24%`

D

`0.33%`

Text Solution

AI Generated Solution

The correct Answer is:
To find the percentage ionization of 0.1 M acetic acid (CH₃COOH) given that 0.01 M acetic acid is 4.24% ionized, we can use the relationship between the degree of ionization (α) and concentration (C) for a weak acid. ### Step-by-Step Solution: 1. **Identify Given Values:** - Concentration of acetic acid (C₁) = 0.01 M - Percentage ionization of 0.01 M acetic acid = 4.24% - Concentration of acetic acid (C₂) = 0.1 M 2. **Convert Percentage Ionization to Degree of Ionization:** - Degree of ionization (α₁) for 0.01 M acetic acid: \[ \alpha_1 = \frac{4.24}{100} = 0.0424 \] 3. **Use the Relationship Between Degrees of Ionization and Concentrations:** - The formula relating the degrees of ionization and concentrations is: \[ \frac{\alpha_1}{\alpha_2} = \sqrt{\frac{C_2}{C_1}} \] - Here, α₂ is the degree of ionization for 0.1 M acetic acid. 4. **Substitute the Values into the Formula:** - Substitute C₁ = 0.01 M and C₂ = 0.1 M into the formula: \[ \frac{0.0424}{\alpha_2} = \sqrt{\frac{0.1}{0.01}} \] - Simplifying the right side: \[ \sqrt{\frac{0.1}{0.01}} = \sqrt{10} \approx 3.1623 \] 5. **Rearranging the Equation to Solve for α₂:** - Rearranging gives: \[ \alpha_2 = \frac{0.0424}{3.1623} \] 6. **Calculate α₂:** - Performing the calculation: \[ \alpha_2 \approx \frac{0.0424}{3.1623} \approx 0.0134 \] 7. **Convert Degree of Ionization Back to Percentage:** - Convert α₂ to percentage: \[ \text{Percentage Ionization} = \alpha_2 \times 100 = 0.0134 \times 100 \approx 1.34\% \] ### Final Answer: The percentage ionization of 0.1 M acetic acid is approximately **1.34%**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

The degree of dissociation of weak electrolyde is inversely proportional to the square root fo concentration. It is called Ostwald's dilution law. alpha = sqrt((K_(a))/(c)) As the tempertaure increases, degree of dissociation will increase. (alpha_(1))/(alpha_(2)) = sqrt((K_(a_(1)))/(K_(a_(2)))) if concentration is same. (alpha_(1))/(alpha_(2)) = sqrt((c_(2))/(c_(1))) if acid is same. 0.01M CH_(3)COOH has 4.24% degree of dissociation, the degree of dissociation of 0.1M CH_(3)COOH will be

Which of the following solutions added to 1L of a 0.01 M CH_(3)COOH solution will cause no change in the degree of dissociation of CH_(3)COOH and pH of the solution ? (K_(a)=1.6xx10^(-5) for CH_(3)COOH)

What amount of solid acetate should be added into 1 litre of the 0.1 M CH_(3)COOH solution so that the resulting solution has pH almost equal to pK_(a) (CH_(3)COOH) = 4.74 .

50 ml of 0.05 M sodium hydroxide is mixed with 50 ml 0.1 of M acetic acid solution. What will be the pH resulting solution if K_(a) (CH_(3)COOH) = 2 xx 10^(-5)

The pH of a buffer solution prepared by adding 10 mL of 0.1 M CH_(3) COOH and 20 mL 0.1 M sodium acetate will be ( given : pK_(a) of CH_(3)COOH = 4.74 )

The enthalpy of neutralisation of NH_(4)OH and CH_(3)COOH is -10.5 kcal mol^(-1) and enthalpy of neutralisation of CH_(3)COOH with strong base is -12.5 kcal mol^(-1) . The enthalpy of ionisation of NH_(4)OH will be

20 ml 0.1M CH_(3),COOH has P^(H) value 3. It is titrated with 0.1M NaOH What is K_(a) of CH_(3)COOH

200 mL of 0.4M solution of CH_(3)COONa is mixed with 400 mL of 0.2 M solution of CH_(3)COOH . After complete mixing, 400 mL of 0.1 M NaCl is added to it. What is the pH of the resulting solution? [K_(a) of CH_(3)COOH=10^(-5)]

Calculate the pH of each of the following solution (i) 100 ml of 0.1 M CH_(3)COOH mixed with 100 ml of 0.1 M NaOH. (ii) 100 ml of 0.1 M CH_(3)COOH mixed with 50 ml of 0.1 m NaOH (iii) 50 ml of 0.1 M CH_(3)COOH mixed with 100 ml of 0.1 M NaOH. K_(a)(CH_(3)COOH)=1.8xx10^(-5)

The dissociation constatn of 0.01 M CH_(3)COOH is 1.8xx10^(-5) then calculate CH_(3)COO^(-) concentration of 0.1 M HCl solution.