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Which of the following has the lowest va...

Which of the following has the lowest value of Ksp at ordinary temperature is?

A

`Mg(OH)_(2)`

B

`Ca(OH)_(2)`

C

`Ba(OH)_(2)`

D

`Be(OH)_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the compounds has the lowest value of Ksp (solubility product constant) at ordinary temperature, we can analyze the compounds given: magnesium hydroxide (Mg(OH)₂), calcium hydroxide (Ca(OH)₂), barium hydroxide (Ba(OH)₂), and beryllium hydroxide (Be(OH)₂). ### Step-by-Step Solution: 1. **Understand Ksp**: Ksp is a measure of the solubility of a compound in water. A lower Ksp value indicates that the compound is less soluble in water. 2. **Identify the Compounds**: The compounds we are comparing are: - Magnesium hydroxide (Mg(OH)₂) - Calcium hydroxide (Ca(OH)₂) - Barium hydroxide (Ba(OH)₂) - Beryllium hydroxide (Be(OH)₂) 3. **Consider the Electronegativity**: The electronegativity of the metal ions affects the solubility of their hydroxides. The order of electronegativity for the metals in these hydroxides is: - Beryllium (Be) > Magnesium (Mg) > Calcium (Ca) > Barium (Ba) 4. **Analyze the Tendency to Lose OH⁻ Ions**: The tendency of these hydroxides to lose OH⁻ ions is inversely related to their electronegativity. Thus, the order of tendency to lose OH⁻ ions is: - Barium hydroxide (Ba(OH)₂) > Calcium hydroxide (Ca(OH)₂) > Magnesium hydroxide (Mg(OH)₂) > Beryllium hydroxide (Be(OH)₂) 5. **Determine Ksp Values**: Since beryllium hydroxide has the highest electronegativity, it has the least tendency to lose OH⁻ ions, which means it is the least soluble. Therefore, it will have the lowest Ksp value among the four hydroxides. 6. **Conclusion**: Based on the analysis, beryllium hydroxide (Be(OH)₂) has the lowest value of Ksp at ordinary temperature. ### Final Answer: Beryllium hydroxide (Be(OH)₂) has the lowest value of Ksp at ordinary temperature. ---
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