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Solubility products of ACO(3), BSO(4), a...

Solubility products of `ACO_(3), BSO_(4)`, and `ASO_(4)`, are `4 xx 10^(-10), 6 xx 10^(-10)` and `8 xx 10^(-10)` respectively. The solubility product of `BCO_(3)`, is x x `10^(-10)`, What is x ?

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To solve the problem, we need to find the value of \( x \) in the solubility product of \( BCO_3 \) given the solubility products of \( ACO_3 \), \( BSO_4 \), and \( ASO_4 \). ### Step 1: Write the dissociation equations 1. For \( ACO_3 \): \[ ACO_3 \rightleftharpoons A^{2+} + CO_3^{2-} \] The solubility product \( K_{sp} \) is given by: \[ K_{sp} = [A^{2+}][CO_3^{2-}] \] 2. For \( BSO_4 \): \[ BSO_4 \rightleftharpoons B^{2+} + SO_4^{2-} \] The solubility product \( K_{sp} \) is given by: \[ K_{sp} = [B^{2+}][SO_4^{2-}] \] 3. For \( ASO_4 \): \[ ASO_4 \rightleftharpoons A^{2+} + SO_4^{2-} \] The solubility product \( K_{sp} \) is given by: \[ K_{sp} = [A^{2+}][SO_4^{2-}] \] ### Step 2: Use the given solubility products - \( K_{sp}(ACO_3) = 4 \times 10^{-10} \) - \( K_{sp}(BSO_4) = 6 \times 10^{-10} \) - \( K_{sp}(ASO_4) = 8 \times 10^{-10} \) ### Step 3: Relate the solubility products From the dissociation of \( ACO_3 \) and \( BSO_4 \), we can set up a relationship between the solubility products: \[ \frac{[CO_3^{2-}]}{[SO_4^{2-}]} = \frac{K_{sp}(ACO_3)}{K_{sp}(ASO_4)} \] Substituting the values: \[ \frac{[CO_3^{2-}]}{[SO_4^{2-}]} = \frac{4 \times 10^{-10}}{8 \times 10^{-10}} = \frac{1}{2} \] This implies: \[ [SO_4^{2-}] = 2[CO_3^{2-}] \] ### Step 4: Write the solubility product for \( BCO_3 \) For \( BCO_3 \): \[ BCO_3 \rightleftharpoons B^{2+} + CO_3^{2-} \] Thus, the solubility product \( K_{sp}(BCO_3) \) is: \[ K_{sp}(BCO_3) = [B^{2+}][CO_3^{2-}] \] ### Step 5: Relate \( [B^{2+}] \) to \( [SO_4^{2-}] \) From \( BSO_4 \): \[ K_{sp}(BSO_4) = [B^{2+}][SO_4^{2-}] \] Substituting for \( [SO_4^{2-}] \): \[ K_{sp}(BSO_4) = [B^{2+}](2[CO_3^{2-}]) \] Thus: \[ 6 \times 10^{-10} = [B^{2+}](2[CO_3^{2-}]) \] This gives: \[ [B^{2+}] = \frac{6 \times 10^{-10}}{2[CO_3^{2-}]} = \frac{3 \times 10^{-10}}{[CO_3^{2-}]} \] ### Step 6: Substitute back to find \( K_{sp}(BCO_3) \) Substituting \( [B^{2+}] \) into the \( K_{sp}(BCO_3) \): \[ K_{sp}(BCO_3) = \left(\frac{3 \times 10^{-10}}{[CO_3^{2-}]}\right)[CO_3^{2-}] = 3 \times 10^{-10} \] ### Conclusion Thus, the solubility product of \( BCO_3 \) is: \[ K_{sp}(BCO_3) = 3 \times 10^{-10} \] Therefore, \( x = 3 \).
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