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The degree of dissociation of 0.1 N CH3 ...

The degree of dissociation of `0.1 N CH_3 COOH` is (given `K_a=1xx10^(-5)`) approximately

A

`10^(-5)`

B

`10^(-4)`

C

`10^(-3)`

D

`10^(-2)`

Text Solution

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The correct Answer is:
To find the degree of dissociation (α) of 0.1 N acetic acid (CH₃COOH) given that the dissociation constant (Kₐ) is 1 × 10⁻⁵, we can use the Ostwald dilution law, which states: \[ \alpha = \sqrt{\frac{K_a}{C}} \] where: - α = degree of dissociation - Kₐ = dissociation constant - C = concentration (normality in this case) ### Step-by-Step Solution: 1. **Identify the given values:** - Kₐ = 1 × 10⁻⁵ - C = 0.1 N (normality) 2. **Convert normality to molarity:** - For acetic acid, the normality is equal to the molarity since the n-factor is 1. - Therefore, C = 0.1 M. 3. **Substitute the values into the formula:** \[ \alpha = \sqrt{\frac{K_a}{C}} = \sqrt{\frac{1 \times 10^{-5}}{0.1}} \] 4. **Calculate the concentration in the formula:** - Convert 0.1 to scientific notation: \[ 0.1 = 1 \times 10^{-1} \] - Thus, we can rewrite the equation: \[ \alpha = \sqrt{\frac{1 \times 10^{-5}}{1 \times 10^{-1}}} = \sqrt{1 \times 10^{-4}} \] 5. **Calculate the square root:** \[ \alpha = \sqrt{10^{-4}} = 10^{-2} \] 6. **Final Result:** - The degree of dissociation (α) is approximately \( 10^{-2} \) or 0.01. ### Conclusion: The degree of dissociation of 0.1 N CH₃COOH is approximately \( 0.01 \) or \( 10^{-2} \). ---
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