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Calculate the solubility of CaF(2) in wa...

Calculate the solubility of `CaF_(2)` in water at 298 K which is 70% dissociated. `K_(sp)` of `CaF_(2)` is `1.7 xx 10^(-10)`. If answer is x `xx 10^(-4)` mol/ltr then x = ____?

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To calculate the solubility of \( \text{CaF}_2 \) in water at 298 K, given that it is 70% dissociated and the \( K_{sp} \) of \( \text{CaF}_2 \) is \( 1.7 \times 10^{-10} \), we can follow these steps: ### Step 1: Write the dissociation equation The dissociation of calcium fluoride in water can be represented as: \[ \text{CaF}_2 (s) \rightleftharpoons \text{Ca}^{2+} (aq) + 2\text{F}^{-} (aq) \] ### Step 2: Define solubility Let the solubility of \( \text{CaF}_2 \) be \( S \) mol/L. Since it is 70% dissociated, the concentrations of the ions will be: - Concentration of \( \text{Ca}^{2+} \): \( S \times \frac{70}{100} = S \times 0.7 \) - Concentration of \( \text{F}^{-} \): \( 2S \times \frac{70}{100} = 2S \times 0.7 = 1.4S \) ### Step 3: Write the expression for \( K_{sp} \) The solubility product constant \( K_{sp} \) is given by: \[ K_{sp} = [\text{Ca}^{2+}][\text{F}^{-}]^2 \] Substituting the concentrations we found: \[ K_{sp} = (0.7S)(1.4S)^2 \] ### Step 4: Substitute \( K_{sp} \) value Substituting the value of \( K_{sp} \): \[ 1.7 \times 10^{-10} = (0.7S)(1.4^2 S^2) \] Calculating \( 1.4^2 \): \[ 1.4^2 = 1.96 \] Thus, we have: \[ 1.7 \times 10^{-10} = 0.7S \cdot 1.96S^2 \] \[ 1.7 \times 10^{-10} = 1.372S^3 \] ### Step 5: Solve for \( S^3 \) Rearranging the equation gives: \[ S^3 = \frac{1.7 \times 10^{-10}}{1.372} \] Calculating the right side: \[ S^3 \approx 1.239 \times 10^{-10} \] ### Step 6: Calculate \( S \) Taking the cube root of both sides: \[ S = \sqrt[3]{1.239 \times 10^{-10}} \approx 4.98 \times 10^{-4} \text{ mol/L} \] ### Step 7: Find the value of \( x \) Since the answer is in the form \( x \times 10^{-4} \) mol/L, we find that: \[ x \approx 4.98 \] ### Final Answer Thus, the value of \( x \) is: \[ \boxed{4.98} \]
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