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(A): Reaction given below is possible ...

(A): Reaction given below is possible
`2KCI + Br_2 to Cl_(2) + 2KBr`
(R): lighter halogen displaces larger halogen from its metal halides .

A

Both A & R are true, R is the correct explanation of A

B

Both A & R are true, R is not correct explanation of A

C

A is true, R is false

D

A is false, R is true

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given question, we will break it down into two parts: (A) the reaction itself and (R) the statement regarding halogens. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is: \[ 2KCl + Br_2 \rightarrow Cl_2 + 2KBr \] Here, potassium chloride (KCl) reacts with bromine (Br2) to produce chlorine (Cl2) and potassium bromide (KBr). **Hint**: Look at the reactants and products to identify which elements are involved in the reaction. 2. **Determine the Reactivity of Halogens**: Halogens are arranged in the periodic table in order of increasing atomic number: Fluorine (F), Chlorine (Cl), Bromine (Br), Iodine (I), and Astatine (At). In this series, the reactivity decreases as you move down the group. Chlorine (Cl) is a lighter halogen compared to bromine (Br), which is a heavier halogen. **Hint**: Remember that lighter halogens are generally more reactive than heavier ones. 3. **Evaluate the Reaction's Feasibility**: According to the reactivity series of halogens, a lighter halogen can displace a heavier halogen from its compounds. In this case, chlorine (Cl) is displacing bromine (Br) from potassium bromide (KBr). Therefore, the reaction should be possible. **Hint**: Use the concept of reactivity series to determine if one halogen can displace another. 4. **Assess Statement (R)**: The statement (R) claims that "a lighter halogen displaces a larger halogen from its metal halides." This is true, as we have established that chlorine (the lighter halogen) can displace bromine (the larger halogen) from potassium bromide. **Hint**: Think about the definitions of "lighter" and "larger" in the context of halogens and their reactivity. 5. **Conclusion**: - (A) The reaction is **not possible** because the heavier halogen (bromine) cannot be displaced by the lighter halogen (chlorine) in this context. - (R) The statement is **true** as lighter halogens can displace larger halogens from their metal halides. Thus, the final assessment is: - (A) is false. - (R) is true. ### Final Answer: - **A** is false, **R** is true. Therefore, the correct option is D.
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