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Which of the following statements about ...

Which of the following statements about halogens is correct?

A

All are diatomic and forms univalent ion

B

All are capable of exhibiting several oxidation states

C

All are diatomic and form divalent ions

D

They can mutually displace each other from the solution of their compounds with metals

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement about halogens is correct, let's analyze each statement step by step. ### Step 1: Analyze the First Statement **Statement:** All are diatomic and form univalent ions. - **Explanation:** Halogens (F, Cl, Br, I) exist as diatomic molecules (e.g., F2, Cl2, Br2, I2) in their elemental form. They typically form univalent ions (e.g., F-, Cl-, Br-, I-) because they have five electrons in their outer p subshell (ns²np⁵) and can gain one electron to achieve a stable octet configuration. **Conclusion:** This statement is correct. ### Step 2: Analyze the Second Statement **Statement:** All are capable of exhibiting several oxidation states. - **Explanation:** While bromine and iodine can exhibit multiple oxidation states (e.g., -1, 0, +1, +3, +5, +7), fluorine only exhibits one oxidation state, which is -1. Therefore, not all halogens can exhibit several oxidation states. **Conclusion:** This statement is incorrect. ### Step 3: Analyze the Third Statement **Statement:** All are diatomic and form divalent ions. - **Explanation:** While halogens are diatomic, they do not form divalent ions. They typically form univalent ions as mentioned earlier. **Conclusion:** This statement is incorrect. ### Step 4: Analyze the Fourth Statement **Statement:** They can mutually displace each other from the solution of their compounds with metals. - **Explanation:** In the halogen group, a more reactive halogen can displace a less reactive halogen from its compound. However, a halogen lower in the group cannot displace a halogen higher in the group. For example, iodine cannot displace fluorine from sodium fluoride. **Conclusion:** This statement is incorrect. ### Final Conclusion The only correct statement about halogens is the **first statement**: "All are diatomic and form univalent ions." ---
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