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4HCI + A to MnCl2 + Cl2 uarr + 2H2O, In ...

`4HCI + A to MnCl_2 + Cl_2 uarr + 2H_2O`, In this reaction the change in oxidation state of metal present in A is 

A

`2` to `-2`

B

`+4` to `+6`

C

`-1` to `+3`

D

`+4` to `+2`

Text Solution

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The correct Answer is:
To determine the change in oxidation state of the metal present in compound A in the reaction \( 4HCl + A \rightarrow MnCl_2 + Cl_2 + 2H_2O \), we will follow these steps: ### Step 1: Identify the oxidation states of chlorine in the reactants and products. - In \( HCl \), the oxidation state of Cl is -1. - In \( Cl_2 \), the oxidation state of Cl is 0. ### Step 2: Determine the change in oxidation state for chlorine. - The oxidation state of Cl changes from -1 in \( HCl \) to 0 in \( Cl_2 \). This indicates that \( HCl \) is being oxidized. ### Step 3: Identify the metal in compound A. - The product \( MnCl_2 \) indicates that the metal in compound A is manganese (Mn). ### Step 4: Determine the oxidation state of manganese in \( MnCl_2 \). - In \( MnCl_2 \), the oxidation state of Cl is -1. Therefore, for \( MnCl_2 \): \[ X + 2(-1) = 0 \implies X - 2 = 0 \implies X = +2 \] - Thus, the oxidation state of Mn in \( MnCl_2 \) is +2. ### Step 5: Determine the oxidation state of manganese in compound A. - We need to deduce the oxidation state of Mn in compound A. Given that \( HCl \) is oxidized and Mn is reduced, we can assume that compound A contains manganese in a higher oxidation state. - A reasonable assumption for compound A is \( MnO_2 \), where the oxidation state of Mn can be calculated as follows: \[ X + 2(-2) = 0 \implies X - 4 = 0 \implies X = +4 \] - Therefore, the oxidation state of Mn in \( MnO_2 \) is +4. ### Step 6: Calculate the change in oxidation state of manganese. - The change in oxidation state of Mn from \( MnO_2 \) (+4) to \( MnCl_2 \) (+2) is: \[ +4 \rightarrow +2 \implies \text{Change} = +4 - (+2) = +2 \] ### Conclusion: The change in oxidation state of the metal present in A (Mn) is **2**. ---
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