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Hybridisation of the central atom in Cl2...

Hybridisation of the central atom in `Cl_2O` molecule is 

A

`sp^2`

B

`sp^3`

C

`sp^3d`

D

`sp^3 d^2`

Text Solution

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The correct Answer is:
To determine the hybridization of the central atom in the Cl₂O molecule, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Central Atom**: In the Cl₂O molecule, the central atom is oxygen (O). Chlorine (Cl) atoms are terminal atoms. 2. **Determine the Valence Electrons**: Oxygen has 6 valence electrons (as it is in group 16 of the periodic table). 3. **Count the Monovalent Atoms**: Chlorine is a monovalent atom, meaning it can form one bond. Since there are two chlorine atoms in Cl₂O, we have 2 monovalent atoms. 4. **Calculate the Hybridization Number (H)**: The hybridization number can be calculated using the formula: \[ H = \frac{(S + M)}{2} \] where: - \(S\) = number of valence electrons of the central atom (O) = 6 - \(M\) = number of monovalent atoms (Cl) = 2 Plugging in the values: \[ H = \frac{(6 + 2)}{2} = \frac{8}{2} = 4 \] 5. **Determine the Hybridization Type**: A hybridization number of 4 corresponds to \(sp^3\) hybridization. This indicates that the central atom (oxygen) forms four hybrid orbitals. 6. **Conclusion**: Therefore, the hybridization of the central atom in the Cl₂O molecule is \(sp^3\). ### Final Answer: The hybridization of the central atom in Cl₂O is \(sp^3\). ---
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