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The shape of XeF6 is...

The shape of `XeF_6` is

A

Pentagonal bipyramidal

B

Square planar

C

Octahedral

D

Distrorted octahedral

Text Solution

AI Generated Solution

The correct Answer is:
To determine the shape of \( \text{XeF}_6 \), we can follow these steps: ### Step 1: Identify the central atom and its valence electrons The central atom in \( \text{XeF}_6 \) is xenon (Xe). Xenon is a noble gas and has 8 valence electrons. ### Step 2: Count the number of fluorine atoms and their contribution Each fluorine (F) atom contributes 1 electron, and since there are 6 fluorine atoms, they contribute a total of 6 electrons. ### Step 3: Calculate the total number of electrons around the central atom The total number of electrons around the xenon atom is: \[ \text{Valence electrons of Xe} + \text{Electrons from F} = 8 + 6 = 14 \text{ electrons} \] ### Step 4: Determine the number of bonding pairs and lone pairs Each bond between xenon and fluorine uses 2 electrons. Since there are 6 fluorine atoms, we have: \[ \text{Bonding pairs} = \frac{6 \text{ bonds} \times 2 \text{ electrons/bond}}{2} = 6 \text{ bonding pairs} \] Now, we have 14 total electrons and 12 electrons used in bonding (6 bonds), leaving us with: \[ \text{Lone pairs} = \frac{14 - 12}{2} = 1 \text{ lone pair} \] ### Step 5: Determine the geometry using VSEPR theory According to VSEPR (Valence Shell Electron Pair Repulsion) theory, the arrangement of electron pairs around the central atom determines the molecular geometry. With 6 bonding pairs and 1 lone pair, the arrangement is based on an octahedral geometry. ### Step 6: Identify the shape of the molecule The presence of the lone pair distorts the ideal octahedral shape. Therefore, the shape of \( \text{XeF}_6 \) is a distorted octahedral geometry. ### Final Answer The shape of \( \text{XeF}_6 \) is **distorted octahedral**. ---
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