To solve the question regarding which compound will not exist among the given options (genon-difluoride, genon-tetrafluoride, genon-hexafluoride, and genon-optafluoride), we can analyze the electronic configuration of the noble gas genon (which is actually xenon, but we'll refer to it as genon as per the question).
### Step-by-Step Solution:
1. **Understand the Electronic Configuration of Genon**:
- Genon has an electronic configuration of 5s² 5p⁶, which means it has a complete outer shell.
**Hint**: Remember that noble gases have complete valence shells, making them generally inert.
2. **Excitation of Electrons**:
- In the first excited state, one electron from the p-orbital can jump to the d-orbital, allowing genon to form bonds with two fluoride ions, resulting in genon-difluoride.
**Hint**: Consider how noble gases can form compounds by promoting electrons to higher energy levels.
3. **Formation of Genon-Tetrafluoride**:
- In the second excited state, two electrons can be promoted, resulting in four half-filled orbitals. This allows genon to bond with four fluoride ions, forming genon-tetrafluoride.
**Hint**: Think about how the number of available orbitals increases with more excited states.
4. **Formation of Genon-Hexafluoride**:
- In the third excited state, four electrons can be promoted, leading to six half-filled orbitals. Thus, genon can bond with six fluoride ions to form genon-hexafluoride.
**Hint**: Keep track of how many fluoride ions can bond based on the number of half-filled orbitals.
5. **Analysis of Genon-Optafluoride**:
- In the fourth excited state, theoretically, eight half-filled orbitals would be expected. However, this configuration is unstable due to steric hindrance, as eight fluorine atoms cannot fit around one genon atom. Therefore, genon-optafluoride cannot exist and decomposes into genon-hexafluoride and fluorine.
**Hint**: Consider the spatial arrangement and steric factors when multiple large atoms are involved.
6. **Conclusion**:
- Based on the analysis, the compound that will not exist is genon-optafluoride.
**Final Answer**: Genon-optafluoride will not exist.