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Density of a crystal is given by :...

Density of a crystal is given by :

A

`(a^(3)xxM)/(zxxN_(0))`

B

`(N_(0)xxM)/(zxxa^(3))`

C

`(zxxM)/(a^(3)xxN_(0))`

D

`(A^(3)xxN^(0))/(zxxM)`

Text Solution

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The correct Answer is:
To find the correct expression for the density of a crystal, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Density**: Density (ρ) is defined as the mass (m) of a substance divided by its volume (V). \[ \rho = \frac{m}{V} \] 2. **Consider a Cubic Unit Cell**: For a cubic unit cell, the volume can be expressed as: \[ V = a^3 \] where \( a \) is the length of one side of the cube. 3. **Mass of the Unit Cell**: The mass of the unit cell is determined by the number of atoms (or particles) it contains. Let \( z \) be the number of atoms per unit cell. The mass of one atom can be represented as \( m \). Therefore, the total mass of the unit cell is: \[ \text{Mass of unit cell} = z \times m \] 4. **Substituting Mass and Volume into Density Formula**: Now, substituting the expressions for mass and volume into the density formula: \[ \rho = \frac{z \times m}{a^3} \] 5. **Relating Atomic Mass to Density**: The mass of one atom can be expressed in terms of the atomic mass (M) and Avogadro's number (\( N_0 \)): \[ m = \frac{M}{N_0} \] where \( M \) is the atomic mass (or molecular mass for compounds). 6. **Final Expression for Density**: Substituting this expression for \( m \) into the density formula gives: \[ \rho = \frac{z \times \left(\frac{M}{N_0}\right)}{a^3} \] This can be rearranged to: \[ \rho = \frac{z \times M}{N_0 \times a^3} \] 7. **Conclusion**: The correct expression for the density of a crystal is: \[ \rho = \frac{z \times M}{N_0 \times a^3} \]
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