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Which among the following is likely to h...

Which among the following is likely to have Schottky defect.

A

`AgCl`

B

`NaCl`

C

`TiCl`

D

`MgCl_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which among the given options is likely to have a Schottky defect, we need to understand the characteristics of Schottky defects and analyze the options based on these characteristics. ### Step-by-Step Solution: 1. **Understanding Schottky Defect**: - A Schottky defect occurs when an equal number of cations and anions are missing from the crystal lattice. This results in vacancies that maintain the electrical neutrality of the solid. - It is typically found in ionic solids where the sizes of cations and anions are similar. 2. **Identifying Characteristics**: - Equal number of cations and anions missing. - Similar ionic sizes (radius ratio close to 1). - High coordination number ratio. - Decrease in density due to the presence of vacancies. 3. **Analyzing Options**: - We need to look at the provided options (not specified in the question) and check if any of them are ionic compounds with similar cation and anion sizes. 4. **Examples of Compounds with Schottky Defect**: - Common examples include NaCl, CsCl, and AgBr. These compounds can exhibit Schottky defects due to their ionic nature and similar ionic sizes. 5. **Conclusion**: - Based on the characteristics and examples, if NaCl is one of the options, it is likely to have a Schottky defect. Therefore, NaCl would be the correct answer.
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