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The formula of an oxide of iron is Fe(0....

The formula of an oxide of iron is `Fe_(0.93)O_(1.00)`.  If the compound has hundred `O^(-2)` ions, then it contains 

A

`93Fe^(+2)" ions"`

B

`93Fe^(+3)" ions"`

C

`79Fe^(+2), 14Fe^(+3)`

D

`93Fe^(+2), 14Fe^(+3)`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine how many iron (Fe) ions are present in the compound \( Fe_{0.93}O_{1.00} \) when there are 100 \( O^{2-} \) ions. ### Step-by-Step Solution: 1. **Understanding the Formula**: The given formula is \( Fe_{0.93}O_{1.00} \). This indicates that for every 1 mole of the compound, there are 0.93 moles of iron and 1 mole of oxygen. 2. **Scaling the Formula**: Since the problem states there are 100 \( O^{2-} \) ions, we can scale the formula. We multiply both the iron and oxygen by 100. \[ Fe_{0.93}O_{1.00} \rightarrow Fe_{93}O_{100} \] 3. **Charge Neutralization**: Each \( O^{2-} \) ion contributes a charge of -2. Therefore, with 100 \( O^{2-} \) ions, the total negative charge is: \[ \text{Total negative charge} = 100 \times (-2) = -200 \] 4. **Positive Charge from Iron**: To neutralize the -200 charge from oxygen, the total positive charge from iron must also be +200. We denote the number of \( Fe^{2+} \) ions as \( x \) and the number of \( Fe^{3+} \) ions as \( 93 - x \) (since there are 93 iron atoms in total). 5. **Setting Up the Charge Equation**: The positive charge contributed by the iron ions can be expressed as: \[ 2x + 3(93 - x) = 200 \] 6. **Solving the Equation**: Expanding the equation gives: \[ 2x + 279 - 3x = 200 \] Rearranging terms: \[ -x + 279 = 200 \] \[ -x = 200 - 279 \] \[ -x = -79 \quad \Rightarrow \quad x = 79 \] 7. **Finding the Number of Iron Ions**: Since \( x = 79 \), this means there are 79 \( Fe^{2+} \) ions. The remaining iron ions are \( 93 - 79 = 14 \), which are \( Fe^{3+} \) ions. ### Final Answer: The compound contains **79 \( Fe^{2+} \) ions** and **14 \( Fe^{3+} \) ions**.
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