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Ar crystallizes in a F.C.C lattice with ...

Ar crystallizes in a F.C.C lattice with one atom at each lattice point. If the edge length is `5.311A^(0)` at OK, the distance between nearest neighbouring atoms in Ar at 'O'K is 

A

`3.755A^(@)`

B

`7.355A^(@)`

C

`5.735A^(@)`

D

`1.877^(@)`

Text Solution

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The correct Answer is:
To find the distance between nearest neighboring atoms in Argon (Ar) which crystallizes in a Face-Centered Cubic (FCC) lattice, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the FCC Lattice Structure**: - In an FCC lattice, atoms are located at each corner of the cube and at the center of each face. This means there are atoms at 8 corners and 6 face centers. 2. **Identify the Edge Length**: - The edge length (a) of the FCC unit cell is given as 5.311 Å (angstrom). 3. **Calculate the Face Diagonal**: - The formula for the face diagonal (d) in an FCC lattice is: \[ d = \sqrt{2} \times a \] - Substituting the value of edge length: \[ d = \sqrt{2} \times 5.311 \, \text{Å} \] 4. **Calculate the Distance Between Nearest Neighbors**: - The nearest neighbors in an FCC lattice are located along the face diagonal. The distance between nearest neighboring atoms is half of the face diagonal: \[ \text{Distance} = \frac{d}{2} = \frac{\sqrt{2} \times a}{2} \] - This simplifies to: \[ \text{Distance} = \frac{a}{\sqrt{2}} \] - Now substituting the edge length: \[ \text{Distance} = \frac{5.311 \, \text{Å}}{\sqrt{2}} \] 5. **Final Calculation**: - Calculate the numerical value: \[ \text{Distance} \approx \frac{5.311}{1.414} \approx 3.755 \, \text{Å} \] ### Conclusion: The distance between nearest neighboring atoms in Argon at 0 K is approximately **3.755 Å**.
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