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Paramagnetic oxide is...

Paramagnetic oxide is

A

`N_(2)O`

B

`N_(2)O_(3)`

C

`NO`

D

`N_(2)O_(4)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given oxides is paramagnetic, we need to analyze the number of electrons in each compound and check for the presence of unpaired electrons. A species is considered paramagnetic if it has one or more unpaired electrons. ### Step-by-Step Solution: 1. **Identify the Compounds**: The options provided are: - A) N2O - B) N2O3 - C) NO - D) N2O4 2. **Calculate the Total Number of Electrons for Each Compound**: - **For N2O**: - Nitrogen (N) has 7 electrons, and there are 2 nitrogen atoms: 2 × 7 = 14 electrons. - Oxygen (O) has 8 electrons: 1 × 8 = 8 electrons. - Total = 14 + 8 = 22 electrons (even). - **For N2O3**: - Nitrogen (N): 2 × 7 = 14 electrons. - Oxygen (O): 3 × 8 = 24 electrons. - Total = 14 + 24 = 38 electrons (even). - **For NO**: - Nitrogen (N): 7 electrons. - Oxygen (O): 8 electrons. - Total = 7 + 8 = 15 electrons (odd). - **For N2O4**: - N2O4 is a dimer of NO2. - Each NO2 has: N (7) + O (16) = 23 electrons. - Since N2O4 consists of two NO2 units, total = 2 × 23 = 46 electrons (even). 3. **Determine Paramagnetism**: - A species is paramagnetic if it has an odd number of electrons, which indicates the presence of unpaired electrons. - From the calculations: - N2O: 22 electrons (not paramagnetic) - N2O3: 38 electrons (not paramagnetic) - NO: 15 electrons (paramagnetic) - N2O4: 46 electrons (not paramagnetic) 4. **Conclusion**: The only compound that is paramagnetic among the options is **C) NO**. ### Final Answer: The paramagnetic oxide is **C) NO**. ---
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