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The following are some statements about ...

The following are some statements about oxyacids of VA group elements
i) The salt of nitric acid contains `NO_(3)^(-)` ion
ii) The salt of phosphoric acid contains `PO_(4)^(3-)` ion
iii) Salts of meta phosphoric acid contains `HPO_(3)^(2-)` ion The correct combination is

A

All are correct

B

i, iii are correct

C

ii, iii are correct

D

i, ii are correct

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the oxyacids of VA group elements and their corresponding salts, we will analyze each statement step by step. ### Step 1: Analyze the first statement **Statement:** The salt of nitric acid contains `NO3^(-)` ion. **Explanation:** - Nitric acid (HNO3) is a strong acid that dissociates in water to produce one hydrogen ion (H⁺) and one nitrate ion (NO3⁻). - Therefore, when nitric acid reacts with a base (like sodium hydroxide), it forms sodium nitrate (NaNO3) and water (H2O). - The resulting salt, sodium nitrate, contains the nitrate ion (NO3⁻). **Conclusion:** The first statement is correct. ### Step 2: Analyze the second statement **Statement:** The salt of phosphoric acid contains `PO4^(3-)` ion. **Explanation:** - Phosphoric acid (H3PO4) is a triprotic acid, meaning it can donate three protons (H⁺). - When it reacts with a base, it can form a salt such as sodium phosphate (Na3PO4). - In solution, sodium phosphate dissociates into three sodium ions (Na⁺) and one phosphate ion (PO4³⁻). **Conclusion:** The second statement is also correct. ### Step 3: Analyze the third statement **Statement:** Salts of metaphosphoric acid contain `HPO3^(2-)` ion. **Explanation:** - Metaphosphoric acid (HPO3) can exist in various forms, including trimeric or polymeric forms. - When metaphosphoric acid loses protons, it can form different ions, such as PO3²⁻ or P3O9³⁻, depending on the number of protons lost. - However, the statement claims that salts contain the HPO3²⁻ ion, which is not typically the case. Instead, salts of metaphosphoric acid would generally contain PO3²⁻ ions or other forms, but not specifically HPO3²⁻. **Conclusion:** The third statement is incorrect. ### Final Conclusion Based on the analysis: - Statement 1 is correct. - Statement 2 is correct. - Statement 3 is incorrect. Thus, the correct combination of statements is **1 and 2**.
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