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The hybridization of sulphur in SO(2) is...

The hybridization of sulphur in `SO_(2)` is: 

A

`sp`

B

`sp^(3)`

C

`sp^(2)`

D

`dsp^(2)`

Text Solution

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The correct Answer is:
To determine the hybridization of sulfur in sulfur dioxide (SO₂), we can follow these steps: ### Step 1: Identify the central atom The central atom in the molecule SO₂ is sulfur (S). ### Step 2: Determine the number of valence electrons Sulfur is in group 16 of the periodic table, which means it has 6 valence electrons. ### Step 3: Count the number of bonded atoms In SO₂, sulfur is bonded to two oxygen atoms. Each oxygen atom forms a double bond with sulfur, but for hybridization purposes, we consider the number of bonded atoms, which is 2. ### Step 4: Calculate the steric number The steric number (SN) can be calculated using the formula: \[ \text{SN} = \text{Number of valence electrons of central atom} + \text{Number of monovalent atoms} \] In this case: - Number of valence electrons of sulfur = 6 - Number of monovalent atoms (which are single-bonded) = 0 (since both bonds with oxygen are double bonds). Thus, the steric number is: \[ \text{SN} = 6 + 0 = 6 \] ### Step 5: Determine the hybridization The hybridization can be determined based on the steric number: - A steric number of 3 corresponds to sp² hybridization. Therefore, the hybridization of sulfur in SO₂ is **sp²**. ### Final Answer: The hybridization of sulfur in SO₂ is **sp²**. ---
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