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When O(3) is passed through an aqueous s...

When `O_(3)` is passed through an aqueous solution of KI, the pH of the resulting solution is

A

7

B

6.8

C

2.8

D

4.2

Text Solution

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The correct Answer is:
To determine the pH of the solution when ozone (O₃) is passed through an aqueous solution of potassium iodide (KI), we can follow these steps: ### Step 1: Identify the Reaction When ozone is introduced into an aqueous solution of KI, it reacts with potassium iodide. The reaction can be represented as: \[ 3 O_3 + 2 KI + 3 H_2O \rightarrow 3 O_2 + I_2 + 2 KOH \] ### Step 2: Analyze the Products From the reaction, we can see that the products include: - Oxygen gas (O₂) - Iodine (I₂) - Potassium hydroxide (KOH) ### Step 3: Determine the Nature of the Solution Potassium hydroxide (KOH) is a strong base. However, the presence of iodine (I₂) is also significant. Iodine in solution can lead to the formation of iodide ions (I⁻) and can also affect the acidity of the solution. ### Step 4: Assess the Oxidation State Changes In this reaction, the oxidation state of iodine changes from -1 in KI to 0 in I₂, indicating that oxidation has occurred. The formation of I₂ from KI indicates that the solution will have a certain acidity due to the presence of iodine. ### Step 5: Determine the pH The presence of I₂ in the solution gives it a reddish color, which is indicative of an acidic environment. The pH of the resulting solution will be less than 7. ### Conclusion Based on the reaction and the products formed, we can conclude that the pH of the resulting solution when O₃ is passed through an aqueous solution of KI will be approximately between 6 to 7, indicating that it is slightly acidic. ### Final Answer The pH of the resulting solution is approximately 6 to 7. ---
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