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The transition element that has stable c...

The transition element that has stable configuration in `+1` oxidation state is

A

Cu

B

Zn

C

Sc

D

Mn

Text Solution

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The correct Answer is:
To determine which transition element has a stable configuration in the +1 oxidation state, we will analyze the electronic configurations of the given options: copper, zinc, scandium, and manganese. ### Step-by-Step Solution: 1. **Identify the Atomic Numbers and Electronic Configurations:** - **Copper (Cu)**: Atomic number = 29 - Electronic configuration: \(1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^1, 3d^{10}\) - **Zinc (Zn)**: Atomic number = 30 - Electronic configuration: \(1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 3d^{10}, 4s^2\) - **Scandium (Sc)**: Atomic number = 21 - Electronic configuration: \(1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 3d^3\) - **Manganese (Mn)**: Atomic number = 25 - Electronic configuration: \(1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 3d^5, 4s^2\) 2. **Determine the +1 Oxidation State Configurations:** - **Copper (Cu)**: - In +1 oxidation state (Cu\(^+\)), it loses one electron from the 4s orbital: - Configuration: \(3d^{10}\) (stable configuration) - **Zinc (Zn)**: - In +1 oxidation state (Zn\(^+\)), it loses one electron from the 4s orbital: - Configuration: \(3d^{10}, 4s^1\) (not stable, as it prefers to lose both 4s electrons to become Zn\(^2+\)) - **Scandium (Sc)**: - In +1 oxidation state (Sc\(^+\)), it loses one electron from the 3d orbital: - Configuration: \(3d^2\) (not stable) - **Manganese (Mn)**: - In +1 oxidation state (Mn\(^+\)), it loses one electron from the 4s orbital: - Configuration: \(3d^5, 4s^1\) (not stable) 3. **Conclusion:** - Among the elements analyzed, only **Copper (Cu)** has a stable electronic configuration in the +1 oxidation state, which is \(3d^{10}\). ### Final Answer: The transition element that has a stable configuration in the +1 oxidation state is **Copper (Cu)**.
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