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Coloured ion among the following is...

Coloured ion among the following is

A

`Zn^(2+)`

B

`Mn^(2+)`

C

`Cu^(1+)`

D

`Ti^(4+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given ions is colored, we need to analyze their electronic configurations and check for the presence of unpaired d electrons. Colored ions typically arise from transition metals that have unpaired d electrons, as these electrons can transition between different energy levels when exposed to light, leading to the absorption of certain wavelengths and the appearance of color. ### Step-by-step Solution: 1. **Identify the Ions**: The ions provided are Zn²⁺, Mg²⁺, Cu⁺, and Ti⁴⁺. 2. **Write the Electron Configurations**: - **Zn²⁺**: The atomic number of Zinc (Zn) is 30. The electron configuration is: - Zn: [Ar] 3d¹⁰ 4s² - Zn²⁺: [Ar] 3d¹⁰ (loses 2 electrons from 4s) - **Mg²⁺**: The atomic number of Magnesium (Mg) is 12. The electron configuration is: - Mg: [Ne] 3s² - Mg²⁺: [Ne] (loses 2 electrons from 3s) - **Cu⁺**: The atomic number of Copper (Cu) is 29. The electron configuration is: - Cu: [Ar] 3d¹⁰ 4s¹ - Cu⁺: [Ar] 3d¹⁰ (loses 1 electron from 4s) - **Ti⁴⁺**: The atomic number of Titanium (Ti) is 22. The electron configuration is: - Ti: [Ar] 3d² 4s² - Ti⁴⁺: [Ar] (loses all 4 electrons from 4s and 3d) 3. **Check for Unpaired Electrons**: - **Zn²⁺**: 3d¹⁰ → All electrons are paired (no color). - **Mg²⁺**: [Ne] → No d electrons (no color). - **Cu⁺**: 3d¹⁰ → All electrons are paired (no color). - **Ti⁴⁺**: [Ar] → No d electrons (no color). 4. **Conclusion**: None of the ions have unpaired d electrons. However, if we were to consider a related ion, Mn²⁺ (which is not listed), it would have unpaired electrons and thus would be colored. Among the provided options, none are colored ions. ### Final Answer: None of the given ions (Zn²⁺, Mg²⁺, Cu⁺, Ti⁴⁺) are colored.
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