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Permanganate ion is not isostructural wi...

Permanganate ion is not isostructural with

A

managanate ion

B

Cromate ion

C

Chlorate ion

D

Perchlorate ion

Text Solution

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The correct Answer is:
To solve the question "Permanganate ion is not isostructural with," we need to analyze the structures of various ions mentioned in the video transcript. ### Step-by-Step Solution: 1. **Identify the Structure of Permanganate Ion (MnO4⁻):** - The permanganate ion (MnO4⁻) has a tetrahedral structure. This is due to the arrangement of four oxygen atoms around the manganese atom, with one of the oxygen atoms having a negative charge. 2. **Identify the Structure of Manganate Ion (MnO4²⁻):** - The manganate ion (MnO4²⁻) also has a tetrahedral structure. It consists of manganese bonded to four oxygen atoms, similar to the permanganate ion. 3. **Identify the Structure of Chromate Ion (CrO4²⁻):** - The chromate ion (CrO4²⁻) has a tetrahedral structure as well. It consists of chromium bonded to four oxygen atoms, which is analogous to both permanganate and manganate. 4. **Identify the Structure of Chlorate Ion (ClO3⁻):** - The chlorate ion (ClO3⁻) has a trigonal pyramidal structure. It consists of a chlorine atom bonded to three oxygen atoms, with one of the oxygen atoms having a double bond and two lone pairs on the chlorine atom. 5. **Identify the Structure of Perchlorate Ion (ClO4⁻):** - The perchlorate ion (ClO4⁻) has a tetrahedral structure. It consists of a chlorine atom bonded to four oxygen atoms, similar to the permanganate ion. 6. **Conclusion:** - Among the ions discussed, the permanganate ion (MnO4⁻) is not isostructural with the chlorate ion (ClO3⁻) because the chlorate ion has a trigonal pyramidal structure, while the permanganate ion has a tetrahedral structure. ### Final Answer: Permanganate ion is not isostructural with **chlorate ion (ClO3⁻)**.
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