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KMnO(4) is powerful oxidant where it con...

`KMnO_(4)` is powerful oxidant where it converts into

A

`MnO_(4)^(2-)`

B

`MnO_(2)`

C

`Mn^(2+)`

D

`Mn^(3+)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the conversion of KMnO₄ (potassium permanganate) as a powerful oxidant, we will analyze its behavior in different mediums: acidic, alkaline, and neutral. ### Step-by-Step Solution: 1. **Understanding KMnO₄ as an Oxidizing Agent**: - KMnO₄ contains manganese in the +7 oxidation state (MnO₄⁻). It is known for its strong oxidizing properties. 2. **Reaction in Acidic Medium**: - When KMnO₄ is added to an acidic medium (for example, sulfuric acid), it undergoes reduction. - The reaction can be represented as: \[ 2KMnO₄ + 3H₂SO₄ \rightarrow K₂SO₄ + 2MnSO₄ + 3H₂O + 5O \] - In this reaction, KMnO₄ is reduced to Mn²⁺ (manganese in +2 oxidation state). 3. **Reaction in Alkaline Medium**: - In a strongly alkaline medium (for example, with potassium hydroxide), KMnO₄ reacts to form manganate ions (MnO₄²⁻). - The reaction can be represented as: \[ 2KMnO₄ + 2KOH \rightarrow 2K₂MnO₄ + H₂O \] - Here, KMnO₄ is converted to K₂MnO₄, which contains manganese in the +6 oxidation state (MnO₄²⁻). 4. **Reaction in Neutral Medium**: - In a neutral medium, KMnO₄ can also react with water, accepting electrons. - The reaction can be represented as: \[ 2KMnO₄ + 4H₂O \rightarrow 2MnO₂ + 4OH⁻ + 2K⁺ \] - In this case, KMnO₄ is reduced to MnO₂ (manganese in +4 oxidation state). 5. **Summary of Conversions**: - In acidic medium: KMnO₄ → Mn²⁺ - In alkaline medium: KMnO₄ → MnO₄²⁻ - In neutral medium: KMnO₄ → MnO₂ ### Final Conclusion: KMnO₄ acts as a powerful oxidizing agent and can convert into different manganese species depending on the medium: - In acidic medium, it converts to Mn²⁺. - In strongly alkaline medium, it converts to MnO₄²⁻. - In neutral medium, it converts to MnO₂.
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