A transitional metal `X^(+2)` in its hydrated state has six 3d electrons. The colour of ion is expected as
A transitional metal `X^(+2)` in its hydrated state has six 3d electrons. The colour of ion is expected as
A
Green
B
Pink
C
Blue
D
Yellow
Text Solution
AI Generated Solution
The correct Answer is:
To determine the expected color of the transition metal ion \( X^{2+} \) with six 3d electrons in its hydrated state, we can follow these steps:
### Step 1: Identify the electronic configuration of the ion
- Since \( X^{2+} \) has six 3d electrons, we first need to write the electronic configuration of the neutral atom \( X \).
- The neutral atom will have two additional electrons compared to the \( X^{2+} \) ion, which means it will have a total of 8 3d electrons (6 in 3d and 2 in 4s).
- The electronic configuration of \( X \) can be written as:
\[
[Ar] \, 3d^6 \, 4s^2
\]
### Step 2: Determine the atomic number of the metal
- The atomic number of the element can be calculated by adding the number of electrons in the configuration:
- Argon (Ar) has an atomic number of 18.
- Therefore, the total atomic number of \( X \) is:
\[
18 + 6 + 2 = 26
\]
- Thus, \( X \) corresponds to iron (Fe), which has an atomic number of 26.
### Step 3: Identify the oxidation state and color of the ion
- In the \( +2 \) oxidation state, the electronic configuration of \( Fe^{2+} \) will be:
\[
[Ar] \, 3d^6 \, 4s^0
\]
- The presence of 6 electrons in the 3d subshell indicates that this ion can exhibit color due to d-d transitions.
### Step 4: Determine the expected color of \( Fe^{2+} \)
- The color of \( Fe^{2+} \) in its hydrated state is known to be light green.
- Therefore, the expected color of the ion \( X^{2+} \) is light green.
### Final Answer
The color of the ion \( X^{2+} \) is expected to be **light green**.
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The IUPAC definition of a transition element is that it is an element that has an incomplete d-subshell in either the neutral atom or its ion. Thus the group 12 elements are member of the d-block but are not transition elements. Chemically solft members of the d-block occurs as sulphide minerals and are partially oxidised to obtain the metal, the more electropositive 'hard' metals occurs as oxides and are extracted by reduction. Opposite to p-block elements, the higher oxidation states are favoured by the heavier elements of d-block Metals on the right of the d-block tend to exist in low oxidation states and form complexes with the ligands. Square-planar complexes are common for the platinum metals and gold in oxidation states that yield d^8 electronic configuration, which include RH(I),Ir(I),Pd(II),Pt(II) and Au(III). The most distinctive features/properties of transition metal complex is their wide range of colours.The crystal field theory attributes the colour of the coordination compounds to d-d transition of the electron.It is important to note that (a) in absence of ligand, crystal field spilling does not occur and hence the substances is colourless, (b) the type of ligand also influences the colour of the complexes. Which of the following has dsp^2 hybridisation and is diamagnetic in nature ? (i) Na_4[Cr(CO)_4] , (ii) [Ni(DMGH)_2] , (iii) [PtHBr(PEt_3)_2] (iv) [As(SCN)_4]^(3-) , (v) [AuBr_4]^(-)
Paramagnetism is a property due to the presence of unpaired electrons. In case of transition metals, as they contain unpaired electrons in the (n-1) d orbitals,most of the transition metal ions and their compounds are paramagnetic .Para magnetism increases with increases in number of unpaired electrons. Magnetic moment is calculated from spin only formula' Vz mu=sqrt(n(n+2)) B.M n="number of unpaired electrons" Similarly the colour of the compounds of transition metals may be attributed to the presence of incomplete (n-1) d sub-shell. When an electron from a lower energy of d-orbitals is excited to a higher energy d-orbital, the energy of excitation corresponds to the frequency of light absorbed. This frequency generally lies in the visible region. The colour observed corresponds to complementary colour of the light observed. The frequency of the light absorbed is determined by the nature of the ligand. Which of the following pair of Compounds is expected to exhibit same colour in aqueous solution
The magnetic moment of a transition metal ion is 3.87BM. The number of unpaired electrons present in it is
The magnetic moment of a transition metal ion is found to be 3.87 Bohr Magneton (BM). The number of unpaired electrons present in it is:
Transition metal compounds are usually coloured This is due to the electronic transition .
The transition element ( with few exceptions ) show a large number of oxidation states . The various oxidation states are related to the electronic configuration of their atoms. The variable oxidation states of a transition metal is due to the involvement of (n-1)d and outer ns electrons . For the first five elements of 3d transition series , the minimum oxidation state is equal to the number of electrons in 4s shell and the maximum oxidation state is equal to the sum of 4s and 3d electrons. The relative stability of various oxidation states of a given element can be explained on the basis of stability of d^(0),d^(5) and d^(10) configuration . In 3d series, the maximum oxidation state is shown by
The transition element ( with few exceptions ) show a large number of oxidation states . The various oxidation states are related to the electronic configuration of their atoms. The variable oxidation states of a transition metal is due to the involvement of (n-1)d and outer ns electrons . For the first five elements of 3d transition series , the minimum oxidation state is equal to the number of electrons in 4s shell and the maximum oxidation state is equal to the sum of 4s and 3d electrons. The relative stability of various oxidation states of a given element can be explained on the basis of stability of d^(0),d^(5) and d^(10) configuration . In which of the following pairs , the first species is more stable than second one
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