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If in Hydrogen atom, an electron jumps f...

If in Hydrogen atom, an electron jumps from `n_(2) = 2` to `n_(1) = 1` in Bohr's orbit, then the value of wave number of the emitted photon will be `(R = 109700 cm^(-1))`

A

`54850 cm^(-1)`

B

`82275 cm^(-1)`

C

`62875 cm^(-1)`

D

`10970 cm^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the wave number of the emitted photon when an electron in a hydrogen atom jumps from \( n_2 = 2 \) to \( n_1 = 1 \), we can use the Rydberg formula for hydrogen: \[ \bar{\nu} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] Where: - \( \bar{\nu} \) is the wave number, - \( R \) is the Rydberg constant (given as \( 109700 \, \text{cm}^{-1} \)), - \( n_1 \) is the lower energy level, - \( n_2 \) is the higher energy level. ### Step 1: Identify the values of \( n_1 \) and \( n_2 \) From the problem, we have: - \( n_1 = 1 \) - \( n_2 = 2 \) ### Step 2: Substitute the values into the Rydberg formula Substituting the values into the formula gives: \[ \bar{\nu} = 109700 \left( \frac{1}{1^2} - \frac{1}{2^2} \right) \] ### Step 3: Calculate the fractions Calculating the fractions: \[ \frac{1}{1^2} = 1 \] \[ \frac{1}{2^2} = \frac{1}{4} \] ### Step 4: Substitute the fractions back into the equation Now substituting these values back into the equation: \[ \bar{\nu} = 109700 \left( 1 - \frac{1}{4} \right) \] ### Step 5: Simplify the expression Now simplify the expression inside the parentheses: \[ 1 - \frac{1}{4} = \frac{4}{4} - \frac{1}{4} = \frac{3}{4} \] ### Step 6: Final calculation Now we can calculate: \[ \bar{\nu} = 109700 \times \frac{3}{4} \] Calculating this gives: \[ \bar{\nu} = 109700 \times 0.75 = 82275 \, \text{cm}^{-1} \] ### Conclusion Thus, the wave number of the emitted photon when the electron jumps from \( n_2 = 2 \) to \( n_1 = 1 \) is: \[ \bar{\nu} = 82275 \, \text{cm}^{-1} \] ### Answer The correct answer is option 2: \( 82275 \, \text{cm}^{-1} \). ---
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