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The radial probability distribution curv...

The radial probability distribution curve obtained for an orbital wave function has 3 peaks and 2 radial nodes. The valence electron of which one of the following metals does this wave function correspond to ? 

A

Cu

B

Li

C

K

D

Na

Text Solution

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The correct Answer is:
To determine the valence electron configuration corresponding to the given radial probability distribution curve with 3 peaks and 2 radial nodes, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Given Information**: - The radial probability distribution curve has 3 peaks, indicating the principal quantum number (n) is 3. - There are 2 radial nodes. 2. **Relate Nodes to Quantum Numbers**: - The number of radial nodes can be calculated using the formula: \[ \text{Number of radial nodes} = n - l - 1 \] - Given that there are 2 radial nodes, we can set up the equation: \[ 2 = n - l - 1 \] - Substituting \( n = 3 \): \[ 2 = 3 - l - 1 \implies l = 0 \] 3. **Identify the Orbital**: - With \( n = 3 \) and \( l = 0 \), the corresponding orbital is the 3s orbital. 4. **Determine the Valence Electron Configuration**: - Now, we need to find which of the given metals has its valence electron in the 3s orbital. The metals provided are: - Copper (Cu, atomic number 29) - Lithium (Li, atomic number 3) - Potassium (K, atomic number 19) - Sodium (Na, atomic number 11) 5. **Write the Electron Configurations**: - **Copper (Cu)**: - Atomic number 29: \( 1s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^1 \) (Valence electron in 4s) - **Lithium (Li)**: - Atomic number 3: \( 1s^2 2s^1 \) (Valence electron in 2s) - **Potassium (K)**: - Atomic number 19: \( 1s^2 2s^2 2p^6 3s^2 3p^6 4s^1 \) (Valence electron in 4s) - **Sodium (Na)**: - Atomic number 11: \( 1s^2 2s^2 2p^6 3s^1 \) (Valence electron in 3s) 6. **Identify the Correct Metal**: - From the configurations, only Sodium (Na) has its valence electron in the 3s orbital. ### Conclusion: The valence electron of the metal that corresponds to the given wave function is Sodium (Na).
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