`Al Cl_3` is

A

Anhydrous and covalent

B

Anhydrous and ionic

C

Covalent and basic

D

Coordinate and acidic

Text Solution

AI Generated Solution

The correct Answer is:
To determine the nature of \( \text{AlCl}_3 \), we will analyze its properties step by step. ### Step 1: Identify the nature of \( \text{AlCl}_3 \) - **Anhydrous Nature**: \( \text{AlCl}_3 \) is referred to as anhydrous because it does not contain water molecules in its structure. This is significant in understanding its behavior in different states. ### Step 2: Analyze the bonding type - **Covalent Nature**: \( \text{AlCl}_3 \) is primarily covalent in nature. This is because aluminum (Al) and chlorine (Cl) share electrons to form covalent bonds. The covalent character is more pronounced due to the small size and high charge density of the aluminum ion. ### Step 3: Consider its behavior in different states - **Ionic Behavior in Aqueous Medium**: When \( \text{AlCl}_3 \) is dissolved in water, it dissociates into ions. This means that in an aqueous solution, it behaves as an ionic compound: \[ \text{AlCl}_3 \rightarrow \text{Al}^{3+} + 3\text{Cl}^- \] ### Step 4: Examine its vapor phase - **Dimer Formation in Vapor Phase**: In the vapor phase, \( \text{AlCl}_3 \) exists as a dimer, which can be represented as: \[ 2\text{AlCl}_3 \rightarrow \text{Al}_2\text{Cl}_6 \] This dimerization occurs due to the covalent nature of the compound, leading to the formation of a stable dimer. ### Conclusion Based on the analysis, we conclude that \( \text{AlCl}_3 \) is: - Anhydrous - Covalent in nature - Ionic in aqueous solution - Dimeric in vapor phase ### Final Answer Thus, the correct characterization of \( \text{AlCl}_3 \) is that it is **anhydrous and covalent**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

Assertion: Anhydrous AlCl_(3) is covalent while hydrated AlCl_(3) is ionic. Reason: In water AlCl_(3) is presennt as Al_((aq.))^(3+) and Cl_((aq.))^(-) ion.

Anhydrous AlCl_(3) is covalent. From the date given below, predict whether it would remain covalent or become ionic in aqueous solution. (Ionisation energy for Al is 1537 kJ mol^(-1) ) Delta_("hydration") for Al^(3+) = - 4665 kJ mol^(-1) Delta_("hydration") for Cl^(Ө) = - 381 kJ mol^-1 .

Hybridization of Al in AlCl_3 is

Consider the reaction 2Al (g) + 3Cl_(2) (g) rArr 2Al Cl_(3) (g) . The approximate volume of chlorine that would react with 324 g of aluminium at STP is :

Calculate the heat of formation of anhydrous Al_2Cl_6 from the following data: (i) 2Al + 6HCl (aq) to Al_2Cl_6 (aq) + 3H_2(g), DeltaH = - 239.76 kcal (ii) Al_2Cl_6 (s) + aq to Al_2Cl_6(aq), DeltaH = - 153.69 kcal (iii) H_2(g) + Cl_2(g) to 2HCl (g) , DeltaH = -44kcal (iv) HCl (g) + aq to HCl (aq), DeltaH = - 17.31 kcal

In an experiment, 6.67 g of AlCl_(3) was produced and 0.654 g Al remainded unreacted. How many g atoms of Al and Cl_(2) were taken originally (Al = 27, Cl = 35.5) ?

Why boron halides do not exists as a dimer. While AlCl_(3) exists as Al_(2)Cl_(6) ?

In an experiment, 6.67 g of AlCl_(3) was produced and 0.54g Al remained unreacted. How many moles of Al and Cl_(2) were taken originally?

pH of saturated solution of Al(OH)_3 is 9 . The solubility product (K_sp) of Al(OH)_3 is

Arrange BCl_3, AlCl_3, GaCl_3, "In"Cl_3 and TlCl_3 in the decreasing order of the stability of +3 oxidation state.