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What is Z in the following reactions ? ...

What is Z in the following reactions ?
`BCl_3 + H_2 underset(450^@ C)overset(Cu-Al)to X + HCl`
`X overset("methylation")to Z`

A

`(CH_3)BH_2`

B

`(CH_3)_4 B_2 H_2`

C

`(CH_3)_3 B_2 H_3`

D

`(CH_3)_6 B_2`

Text Solution

AI Generated Solution

The correct Answer is:
To determine what Z is in the given reactions, we will break down the steps involved in the reactions of BCl3 with H2 and the subsequent methylation of the product. ### Step 1: Identify the Reaction of BCl3 with H2 The first reaction involves boron trichloride (BCl3) reacting with hydrogen gas (H2) in the presence of a catalyst (Cu-Al) at a high temperature (450°C). **Reaction:** \[ BCl_3 + H_2 \xrightarrow{450^\circ C, Cu-Al} B_2H_6 + HCl \] **Explanation:** When BCl3 reacts with H2, it produces diborane (B2H6) and hydrochloric acid (HCl). ### Step 2: Identify Product X From the first reaction, we can conclude that the product X is diborane (B2H6). ### Step 3: Methylation of X The next step involves the methylation of diborane (B2H6). Methylation typically involves the reaction of diborane with methyl chloride (CH3Cl). **Reaction:** \[ B_2H_6 + 4 CH_3Cl \rightarrow Z + 4 HCl \] **Explanation:** In this reaction, the terminal hydrogen atoms of diborane are replaced by methyl groups from methyl chloride, while the bridge hydrogens remain unchanged. ### Step 4: Identify Product Z The product Z formed from the methylation of diborane is: \[ Z = CH_3B_2H_4 \] This compound is known as dimethyl diborane. ### Final Answer Thus, the final answer for Z is: \[ Z = CH_3B_2H_4 \] ---
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