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The number of bonds present in dimeric A...

The number of bonds present in dimeric `AlCl_3 ` are

A

8

B

3

C

6

D

4

Text Solution

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The correct Answer is:
To determine the number of bonds present in dimeric AlCl₃, we can follow these steps: ### Step 1: Understand the Dimeric Form The dimeric form of AlCl₃ is represented as Al₂Cl₆. This means that two aluminum (Al) atoms and six chlorine (Cl) atoms are involved in the structure. **Hint:** Remember that dimeric compounds consist of two identical units bonded together. ### Step 2: Analyze the Structure In Al₂Cl₆, the aluminum atoms are connected to chlorine atoms. Each aluminum atom can form bonds with chlorine atoms. **Hint:** Visualize the arrangement of atoms to better understand how they are bonded. ### Step 3: Count the Covalent Bonds Each aluminum atom forms three covalent bonds with three chlorine atoms. Therefore, for two aluminum atoms, we have: - 3 Al-Cl bonds from the first Al - 3 Al-Cl bonds from the second Al This gives us a total of 6 covalent bonds (3 + 3 = 6). **Hint:** Focus on the bonds formed between aluminum and chlorine atoms. ### Step 4: Identify the Dative Bonds In addition to the covalent bonds, there are dative (coordinate) bonds formed between the aluminum atoms. Each aluminum atom has a vacant p-orbital that can accept a lone pair of electrons from a chlorine atom. In Al₂Cl₆, there are 2 dative bonds formed: - One dative bond from a chlorine atom of one Al to the other Al. - Another dative bond from a chlorine atom of the second Al to the first Al. **Hint:** Dative bonds occur when one atom donates both electrons to form a bond. ### Step 5: Total Number of Bonds Now, we can add the total number of covalent bonds and dative bonds: - Total covalent bonds = 6 - Total dative bonds = 2 Thus, the total number of bonds in dimeric AlCl₃ is: 6 (covalent) + 2 (dative) = 8 bonds. **Hint:** Always sum up the different types of bonds to get the total. ### Final Answer The number of bonds present in dimeric AlCl₃ is **8**. ---
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