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Structure of -BH2 group is...

Structure of `-BH_2` group is

A

linear

B

planar

C

tetrahedral

D

octahedral

Text Solution

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The correct Answer is:
To determine the structure of the `-BH2` group, we can follow these steps: ### Step 1: Identify the Composition of the `-BH2` Group The `-BH2` group consists of one boron (B) atom and two hydrogen (H) atoms. ### Step 2: Count the Bond Pairs and Lone Pairs In the `-BH2` group, boron typically forms three bonds (one with each hydrogen atom and one with a potential third group or atom). However, in this case, we only have two hydrogen atoms attached to boron. Thus, we have: - Bond pairs: 2 (from the two B-H bonds) - Lone pairs: 0 (boron does not have any lone pairs in this case) ### Step 3: Determine the Hybridization The hybridization can be determined based on the number of bond pairs and lone pairs. Since we have 2 bond pairs and 0 lone pairs, we use the formula: - Hybridization = number of bond pairs + number of lone pairs = 2 + 0 = 2 This corresponds to sp² hybridization. ### Step 4: Predict the Molecular Geometry For sp² hybridization, the molecular geometry is trigonal planar. This means that the atoms are arranged in a flat, triangular shape around the central boron atom. ### Step 5: Consider the Charge If we consider the `-BH2` group as `BH2^-`, we need to account for an additional electron due to the negative charge. This does not change the hybridization or the geometry, as we still have 2 bond pairs and 0 lone pairs. ### Conclusion The structure of the `-BH2` group is **trigonal planar**. ---
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