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Carbon atoms show sp^(2) hybridisation i...

Carbon atoms show `sp^(2)` hybridisation in compounds A and B. A decolourises alkaline potassium pemanganate solution whereas B cannot decolourise the solution. Then A and B are

A

Propene and Ethene

B

Ethene and Benzene

C

Benzene and Ethene

D

Ethene and Propene

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the information given about compounds A and B, which both show `sp²` hybridization in their carbon atoms. ### Step-by-Step Solution: 1. **Identify the Characteristics of Compounds A and B**: - Both compounds A and B have carbon atoms that are `sp²` hybridized. - Compound A can decolorize alkaline potassium permanganate (KMnO₄) solution, while compound B cannot. 2. **Understanding the Reaction with KMnO₄**: - Alkaline potassium permanganate is a strong oxidizing agent. It typically reacts with alkenes (which have carbon-carbon double bonds) to form diols, resulting in the decolorization of the purple KMnO₄ solution. - Compounds that do not react with KMnO₄ are usually either saturated hydrocarbons (like alkanes) or compounds that do not have the necessary functional groups for oxidation. 3. **Analyzing Possible Compounds**: - **Compound A**: Since it decolorizes KMnO₄, it is likely an alkene (like propene or ethene) that can undergo oxidation. - **Compound B**: Since it does not decolorize KMnO₄, it is likely a compound that does not react with KMnO₄, such as benzene, which is an aromatic compound. 4. **Conclusion**: - Based on the above analysis, we can conclude that: - Compound A is likely ethene (C₂H₄) or propene (C₃H₆), as both are alkenes and can decolorize KMnO₄. - Compound B is benzene (C₆H₆), which does not react with KMnO₄ and thus does not decolorize the solution. 5. **Final Answer**: - Therefore, the answer is: - A = Ethene (C₂H₄) - B = Benzene (C₆H₆)
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