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240cc of SO2 gas diffused through a poro...

240cc of `SO_2` gas diffused through a porous membrane in 20 minutes. Under similar conditions, 720 cc of another gas diffused in 30 minutes. Find the molecular mass of the gas.

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To solve the problem, we will use Graham's law of effusion, which states that the rate of diffusion of a gas is inversely proportional to the square root of its molar mass (molecular weight). ### Step-by-Step Solution: 1. **Identify the Given Data:** - Volume of `SO2` = 240 cc - Time for `SO2` = 20 minutes - Volume of unknown gas = 720 cc - Time for unknown gas = 30 minutes 2. **Calculate the Rate of Diffusion:** - The rate of diffusion is given by the formula: \[ \text{Rate} = \frac{\text{Volume}}{\text{Time}} \] - For `SO2`: \[ \text{Rate}_{SO2} = \frac{240 \text{ cc}}{20 \text{ min}} = 12 \text{ cc/min} \] - For the unknown gas: \[ \text{Rate}_{\text{unknown}} = \frac{720 \text{ cc}}{30 \text{ min}} = 24 \text{ cc/min} \] 3. **Apply Graham's Law:** - According to Graham's law: \[ \frac{\text{Rate}_{SO2}}{\text{Rate}_{\text{unknown}}} = \sqrt{\frac{M_{\text{unknown}}}{M_{SO2}}} \] - Where \( M \) is the molecular mass. - Rearranging gives: \[ \frac{12}{24} = \sqrt{\frac{M_{\text{unknown}}}{M_{SO2}}} \] - Simplifying the left side: \[ \frac{1}{2} = \sqrt{\frac{M_{\text{unknown}}}{M_{SO2}}} \] 4. **Square Both Sides:** - Squaring both sides to eliminate the square root: \[ \left(\frac{1}{2}\right)^2 = \frac{M_{\text{unknown}}}{M_{SO2}} \] - This simplifies to: \[ \frac{1}{4} = \frac{M_{\text{unknown}}}{M_{SO2}} \] 5. **Find the Molecular Mass of `SO2`:** - The molecular mass of `SO2` is calculated as follows: - Atomic mass of Sulfur (S) = 32 g/mol - Atomic mass of Oxygen (O) = 16 g/mol - Therefore, for `SO2`: \[ M_{SO2} = 32 + (16 \times 2) = 32 + 32 = 64 \text{ g/mol} \] 6. **Substitute and Solve for \( M_{\text{unknown}} \):** - Substitute \( M_{SO2} \) into the equation: \[ \frac{1}{4} = \frac{M_{\text{unknown}}}{64} \] - Rearranging gives: \[ M_{\text{unknown}} = 64 \times \frac{1}{4} = 16 \text{ g/mol} \] ### Conclusion: The molecular mass of the unknown gas is **16 g/mol**.
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